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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with nitrogen (N)Nitro compounds (RNO2) → 4-nitrophenol

FORMULA:HOC6H4(NO2)
CAS RN:100-02-7
STRUCTURE
(FROM NIST):
InChIKey:BTJIUGUIPKRLHP-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.1×102 Guo and Brimblecombe 2007 M 234)
7.7×102 Tremp et al. 1993 M 9)
3.0×102 Lide and Frederikse 1995 V
2.0×104 Riederer 1990 V
3.0×102 Schwarzenbach et al. 1988 V 9)
9.4×104 Yoshida et al. 1983 V
2.6×104 9100 Parsons et al. 1971 T 168)
9.8 6000 Goldstein 1982 X 116)
1.6 Ryan et al. 1988 C
6.1×103 Hilal et al. 2008 Q
1.5×104 Nirmalakhandan et al. 1997 Q
2.6×104 Abraham et al. 1990 ?

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., and Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291-300, doi:10.1039/P29900000291, 1990.
  • Goldstein, D. J.: Air and steam stripping of toxic pollutants, Appendix 3: Henry's law constants, Tech. Rep. EPA-68-03-002, Industrial Environmental Research Laboratory, Cincinnati, OH, USA, 1982.
  • Guo, X. X. and Brimblecombe, P.: Henry's law constants of phenol and mononitrophenols in water and aqueous sulfuric acid, Chemosphere, 68, 436-444, doi:10.1016/J.CHEMOSPHERE.2007.01.011, 2007.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Lide, D. R. and Frederikse, H. P. R., eds.: CRC Handbook of Chemistry and Physics, 76th Edition, CRC Press, Inc., Boca Raton, FL, 1995.
  • Nirmalakhandan, N., Brennan, R. A., and Speece, R. E.: Predicting Henry's law constant and the effect of temperature on Henry's law constant, Wat. Res., 31, 1471-1481, doi:10.1016/S0043-1354(96)00395-8, 1997.
  • Parsons, G. H., Rochester, C. H., and Wood, C. E. C.: Effect of 4-substitution on the thermodynamics of hydration of phenol and the phenoxide anion, J. Chem. Soc. B, pp. 533-536, doi:10.1039/J29710000533, 1971.
  • Riederer, M.: Estimating partitioning and transport of organic chemicals in the foliage/atmosphere system: discussion of a fugacity-based model, Environ. Sci. Technol., 24, 829-837, doi:10.1021/ES00076A006, 1990.
  • Ryan, J. A., Bell, R. M., Davidson, J. M., and O'Connor, G. A.: Plant uptake of non-ionic organic chemicals from soils, Chemosphere, 17, 2299-2323, doi:10.1016/0045-6535(88)90142-7, 1988.
  • Schwarzenbach, R. P., Stierli, R., Folsom, B. R., and Zeyer, J.: Compound properties relevant for assessing the environmental partitioning of nitrophenols, Environ. Sci. Technol., 22, 83-92, doi:10.1021/ES00166A009, 1988.
  • Tremp, J., Mattrel, P., Fingler, S., and Giger, W.: Phenols and nitrophenols as tropospheric pollutants: Emissions from automobile exhausts and phase transfer in the atmosphere, Water Air Soil Pollut., 68, 113-123, doi:10.1007/BF00479396, 1993.
  • Yoshida, K., Shigeoka, T., and Yamauchi, F.: Non-steady state equilibrium model for the preliminary prediction of the fate of chemicals in the environment, Ecotoxicol. Environ. Saf., 7, 179-190, doi:10.1016/0147-6513(83)90064-7, 1983.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
116) Value given here as quoted by Staudinger and Roberts (1996).
168) It is assumed here that the thermodynamic data refers to the units [mol dm−3] and [atm] as standard states.
234) Value at T = 308 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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