MPG

Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Home

Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesOxygen (O) → ozone

FORMULA:O3
CAS RN:10028-15-6
STRUCTURE
(FROM NIST):
InChIKey:CBENFWSGALASAD-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.0×10−4 2800 Sander et al. 2011 L
1.0×10−4 2800 Sander et al. 2006 L
1.1×10−4 2400 Warneck 2003 L
1.3×10−4 2000 Wilhelm et al. 1977 L
1.1×10−4 2300 Gershenzon et al. 2001 M
1.2×10−4 1400 Sotelo et al. 1989 M
1.1×10−4 2300 Kosak-Channing and Helz 1983 M
Roth and Sullivan 1981 M 8)
1.3×10−4 2000 Briner and Perrottet 1939 M
1.1×10−4 2600 Chameides 1984 T
1.0×10−6 Battino 1981 X 5) 9)
1.2×10−4 Perry and Chilton 1973 X 10)
9.3×10−5 2500 Seinfeld 1986 ? 7)
9.3×10−5 2500 Hoffmann and Jacob 1984 ? 7)

References

  • Battino, R., ed.: IUPAC Solubility Data Series, vol. 7 of Oxygen and Ozone , Pergamon Press, Oxford, England, 1981.
  • Briner, E. and Perrottet, E.: Détermination des solubilités de l'ozone dans l'eau et dans une solution aqueuse de chlorure de sodium; calcul des solubilités de l'ozone atmosphérique dans les eaux, Helv. Chim. Acta, 22, 397-404, doi:10.1002/HLCA.19390220151, 1939.
  • Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89D, 4739-4755, doi:10.1029/JD089ID03P04739, 1984.
  • Gershenzon, M., Davidovits, P., Jayne, J. T., Kolb, C. E., and Worsnop, D. R.: Simultaneous uptake of DMS and ozone on water, J. Phys. Chem. A, 105, 7031-7036, doi:10.1021/JP010696Y, 2001.
  • Hoffmann, M. R. and Jacob, D. J.: Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: An application to nighttime fog water chemistry, in: SO2, NO and NO2 Oxidation Mechanisms: Atmospheric Considerations, edited by Calvert, J. G., pp. 101-172, Butterworth Publishers, Boston, MA, 1984.
  • Kosak-Channing, L. F. and Helz, G. R.: Solubility of ozone in aqueous solutions of 0-0.6 M ionic strength at 5-30 ° C, Environ. Sci. Technol., 17, 145-149, doi:10.1021/ES00109A005, 1983.
  • Perry, R. H. and Chilton, C. H.: Chemical Engineers' Handbook, 5th edition, McGraw-Hill, Inc., 1973.
  • Roth, J. A. and Sullivan, D. E.: Solubility of ozone in water, Ind. Eng. Chem. Fund., 20, 137-140, 1981.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY, 1986.
  • Sotelo, J. L., Beltrán, F. J., Benitez, F. J., and Beltrán-Heredia, J.: Henry's law constant for the ozone-water system, Wat. Res., 23, 1239-1246, doi:10.1016/0043-1354(89)90186-3, 1989.
  • Warneck, P.: The solubility of ozone in water, in: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, edited by Fogg, P. and Sangster, J., pp. 225-228, John Wiley & Sons, Inc., 2003.
  • Wilhelm, E., Battino, R., and Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219-262, doi:10.1021/CR60306A003, 1977.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

5) Value given here as quoted by Lide and Frederikse (1995).
7) Several references are given in the list of Henry's law constants but not assigned to specific species.
8) Roth and Sullivan (1981) found that H depends on the concentration of OH.
9) Value at T = 293 K.
10) Value given here as quoted by Durham et al. (1981).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

* * *

Search Henry's Law Database

Species Search:

Identifier Search:

Reference Search:

* * *

Convert Henry's Law Constants

Convert:

* * *