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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesNitrogen (N) → nitrogen monoxide

FORMULA:NO
TRIVIAL NAME: nitric oxide
CAS RN:10102-43-9
STRUCTURE
(FROM NIST):
InChIKey:MWUXSHHQAYIFBG-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.9×10−5 1600 Warneck and Williams 2012 L
1.9×10−5 1600 Sander et al. 2011 L 25)
1.9×10−5 1600 Sander et al. 2006 L 26)
1.9×10−5 1500 Schwartz and White 1981 L
1.3×10−5 Zafiriou and McFarland 1980 M 27)
2.3×10−5 Komiyama and Inoue 1980 M 28)
1.9×10−5 1500 Komiyama and Inoue 1978 M
1.9×10−5 1600 Winkler 1901 M
1.9×10−5 1400 Young 1981b X 3) 29)
1.9×10−5 1400 Young 1981b X 5)
1.9×10−5 1700 Loomis 1928 C
1500 Kühne et al. 2005 Q
1600 Kühne et al. 2005 ?
1.9×10−5 1700 Dean 1992 ? 6)
1.9×10−5 Seinfeld 1986 ? 7)
1.9×10−5 Andrew and Hanson 1961 ?
Wilhelm et al. 1977 W 30)

References

  • Andrew, S. P. S. and Hanson, D.: The dynamics of nitrous gas absorption, Chem. Eng. Sci., 14, 105-113, doi:10.1016/0009-2509(61)85060-4, 1961.
  • Dean, J. A.: Lange's Handbook of Chemistry, McGraw-Hill, Inc., 1992.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Komiyama, H. and Inoue, H.: Reaction and transport of nitrogen oxides in nitrous acid solutions, J. Chem. Eng. Jpn., 11, 25-32, doi:10.1252/JCEJ.11.25, 1978.
  • Komiyama, H. and Inoue, H.: Absorption of nitrogen oxides into water, Chem. Eng. Sci., 35, 154-161, doi:10.1016/0009-2509(80)80082-0, 1980.
  • Loomis, A. G.: Solubilities of gases in water, in: International Critical Tables of Numerical Data, Physics, Chemistry and Technology, Vol. III, edited by Washburn, E. W., West, C. J., Dorsey, N. E., Bichowsky, F. R., and Klemenc, A., pp. 255-261, McGraw-Hill, Inc., 1928.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Schwartz, S. E. and White, W. H.: Solubility equilibria of the nitrogen oxides and oxyacids in dilute aqueous solution, in: Advances in Environmental Science and Engineering, edited by Pfafflin, J. R. and Ziegler, E. N., vol. 4, pp. 1-45, Gordon and Breach Science Publishers, NY, 1981.
  • Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY, 1986.
  • Warneck, P. and Williams, J.: The Atmospheric Chemist's Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0, 2012.
  • Wilhelm, E., Battino, R., and Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219-262, doi:10.1021/CR60306A003, 1977.
  • Winkler, L. W.: Die Löslichkeit der Gase in Wasser (dritte Abhandlung), Ber. Dtsch. Chem. Ges., 34, 1408-1422, doi:10.1002/CBER.19010340210, 1901.
  • Young, C. L., ed.: IUPAC Solubility Data Series, vol. 8 of Oxides of Nitrogen , Pergamon Press, Oxford, England, 1981b.
  • Zafiriou, O. C. and McFarland, M.: Determination of trace levels of nitric oxide in aqueous solution, Anal. Chem., 52, 1662-1667, doi:10.1021/AC50061A029, 1980.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

3) Value given here as quoted by Fogg and Sangster (2003).
5) Value given here as quoted by Lide and Frederikse (1995).
6) Only the tabulated data between T = 273 K and T = 303 K from Dean (1992) were used to derive H and its temperature dependence. Above T = 303 K, the tabulated data could not be parameterized very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by Sander et al. (1995). The quantities A and α from Dean (1992) were assumed to be identical.
7) Several references are given in the list of Henry's law constants but not assigned to specific species.
25) The H298 and A,B,C data listed in Table 5.4 of Sander et al. (2011) are inconsistent, with 94 % difference.
26) The H298 and A,B,C data listed in Table 5.4 of Sander et al. (2006) are inconsistent, with 94 % difference.
27) Value at T = 297 K.
28) Value at T = 288 K.
29) Erratum for page 269 of Fogg and Sangster (2003): The equation is incorrect and not consistent with the corresponding equation for ln(x): The temperature in the last term must be divided by 100 (i.e. ln(T/100) not ln(T)) and an additional term of ln(100) must be added.
30) The fitting parameters A, B, C, and D in Table I of Wilhelm et al. (1977) do not reproduce the data in their Table III.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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