MPG

Henry's Law Constants

Rolf Sander

This page is obsolete, the new page is here:

https://www.henrys-law.org

Please update your bookmarks!

(This page may still be available for a while, but it won't be updated anymore)

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Home

Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Inorganic species → Nitrogen (N) → dinitrogen tetroxide

FORMULA:N2O4
CAS RN:10544-72-6
STRUCTURE
(FROM NIST):
InChIKey:WFPZPJSADLPSON-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.4×10−2 Schwartz and White 1981 L
2.0×10−2 Komiyama and Inoue 1980 M 28)
1.6×10−2 3500 Komiyama and Inoue 1978 M
3.1×10−2 Andrew and Hanson 1961 M
1.3×10−2 1100 Kramers et al. 1961 M

References

  • Andrew, S. P. S. and Hanson, D.: The dynamics of nitrous gas absorption, Chem. Eng. Sci., 14, 105-113, doi:10.1016/0009-2509(61)85060-4, 1961.
  • Komiyama, H. and Inoue, H.: Reaction and transport of nitrogen oxides in nitrous acid solutions, J. Chem. Eng. Jpn., 11, 25-32, doi:10.1252/JCEJ.11.25, 1978.
  • Komiyama, H. and Inoue, H.: Absorption of nitrogen oxides into water, Chem. Eng. Sci., 35, 154-161, doi:10.1016/0009-2509(80)80082-0, 1980.
  • Kramers, H., Blind, M. P. P., and Snoeck, E.: Absorption of nitrogen tetroxide by water jets, Chem. Eng. Sci., 14, 115-123, doi:10.1016/0009-2509(61)85062-8, 1961.
  • Schwartz, S. E. and White, W. H.: Solubility equilibria of the nitrogen oxides and oxyacids in dilute aqueous solution, in: Advances in Environmental Science and Engineering, edited by Pfafflin, J. R. and Ziegler, E. N., vol. 4, pp. 1-45, Gordon and Breach Science Publishers, NY, 1981.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

28) Value at T = 288 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

* * *

Search Henry's Law Database

Species Search:
Identifier Search:
Reference Search:

* * *

Convert Henry's Law Constants

Convert:

* * *