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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with bromine (Br) → Bromocarbons (C, H, O, N, Br) → 3-bromo-1-propyne

FORMULA:C3H3Br
TRIVIAL NAME: propargyl bromide
CAS RN:106-96-7
STRUCTURE
(FROM NIST):
InChIKey:YORCIIVHUBAYBQ-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
8.8×10−3 4000 Yates and Gan 1998 M
3200 Kühne et al. 2005 Q
4200 Kühne et al. 2005 ?
Fogg and Sangster 2003 W 283)

References

  • Fogg, P. and Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc., 2003.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Yates, S. R. and Gan, J. Y.: Volatility, adsorption, and degradation of propargyl bromide as a soil fumigant, J. Agric. Food Chem., 46, 755-761, doi:10.1021/JF9707849, 1998.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

283) Erratum for page 321 of Fogg and Sangster (2003): Data from Yates and Gan (1998) are cited with a typo. The value at 313.2 K should probably be 4.78×10−6, not 4.78×10−2.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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