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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) → methanoic peroxyacid

FORMULA:HCOOOH
TRIVIAL NAME: peroxyformic acid
CAS RN:107-32-4
STRUCTURE
(FROM NIST):
InChIKey:SCKXCAADGDQQCS-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.9×101 Sauer 1997 M 183)
5.2 HSDB 2015 Q 38)

References

  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Sauer, F.: Bestimmung von H2O2 und organischen Peroxiden in Labor- und Feldmessungen mittels Umkehrphasen-Hochdruck-Flüssigkeitschromatographie und enzymatischer Nachsäulenderivatisierung, Ph.D. thesis, Johannes Gutenberg-Universität, Mainz, Germany, 1997.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

38) Calculated based on the method by Meylan and Howard (1991).
183) Value at T = 278 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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