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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorocarbons (C, H, Cl) → chlorobenzene

FORMULA:C6H5Cl
CAS RN:108-90-7
STRUCTURE
(FROM NIST):
InChIKey:MVPPADPHJFYWMZ-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.7×10−3 3800 Staudinger and Roberts 2001 L
2.7×10−3 3800 Staudinger and Roberts 1996 L
2.9×10−3 Mackay and Shiu 1981 L
3.7×10−3 4400 Hiatt 2013 M
1.7×10−3 1300 Lau et al. 2010 M 89)
2.4×10−3 Li et al. 2008 M
1.5×10−3 2300 Lei et al. 2004 M 122)
2.5×10−3 4300 Dewulf et al. 1999 M
1.9×10−3 Ryu and Park 1999 M
3.6×10−3 Dohnal and Hovorka 1999 M 9)
3.4×10−3 de Wolf and Lieder 1998 M 31)
3.2×10−3 Shiu and Mackay 1997 M
3.5×10−3 Hovorka and Dohnal 1997 M 9)
3.0×10−3 3600 Kondoh and Nakajima 1997 M
1.9×10−3 1700 Park et al. 1997 M
2.9×10−3 Ramachandran et al. 1996 M
3.0×10−3 1900 Khalfaoui and Newsham 1994b M
2.6×10−3 Hoff et al. 1993 M
3.1×10−3 2900 Ettre et al. 1993 M 89)
2.5×10−3 Li and Carr 1993 M
3.1×10−3 2000 Cooling et al. 1992 M
2.4×10−3 4700 Bissonette et al. 1990 M
2.5×10−3 2700 Ashworth et al. 1988 M 103)
2.9×10−3 Hellmann 1987 M 31)
3.1×10−3 Yurteri et al. 1987 M 9)
3.2×10−3 Mackay and Shiu 1981 M
3.0×10−3 3500 Leighton and Calo 1981 M
2.9×10−3 4200 Ervin et al. 1980 M
2.5×10−3 Warner et al. 1980 M
2.6×10−3 Mackay et al. 1979 M
1.6×10−3 Sato and Nakajima 1979b M 19)
2.8×10−3 4900 Hartkopf and Karger 1973 M
2.7×10−3 Mackay et al. 2006b V
2.9×10−3 2400 Fogg and Sangster 2003 V
2.7×10−3 Shiu and Mackay 1997 V
2.8×10−3 Park et al. 1997 V
2.9×10−3 Lide and Frederikse 1995 V
2.7×10−3 Mackay et al. 1993 V
2.7×10−3 Mackay et al. 1992a V
2.5×10−3 Hwang et al. 1992 V
2.7×10−3 Bobra et al. 1985 V
2.7×10−3 Yoshida et al. 1983 V
2.7×10−3 Cabani et al. 1981 V
2.7×10−3 Warner et al. 1980 V
2.2×10−3 Hine and Mookerjee 1975 V
2.7×10−3 Mackay et al. 1979 T
2.5×10−3 2100 Goldstein 1982 X 116)
2.7×10−3 Schüürmann 2000 C 7)
2.7×10−3 Ryan et al. 1988 C
2.5×10−3 Shen 1982 C
4.0×10−3 Hilal et al. 2008 Q
4000 Kühne et al. 2005 Q
2.8×10−3 Delgado and Alderete 2002 Q
1.5×10−3 Myrdal and Yalkowsky 1994 Q
4.2×10−3 Nirmalakhandan and Speece 1988a Q
1.8×10−3 Arbuckle 1983 Q
4000 Kühne et al. 2005 ?
2.6×10−3 Mackay et al. 1993 ?
2.2×10−3 Yaws and Yang 1992 ? 92)
2.8×10−3 Abraham et al. 1990 ?
3.8×10−3 Mackay and Yeun 1983 ?

References

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  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Khalfaoui, B. and Newsham, D. M. T.: Determination of infinite dilution activity coefficients and second virial coefficients using gas-liquid chromatography I. The dilute mixtures of water and unsaturated chlorinated hydrocarbons and of water and benzene, J. Chromatogr. A, 673, 85-92, doi:10.1016/0021-9673(94)87060-8, 1994b.
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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

7) Several references are given in the list of Henry's law constants but not assigned to specific species.
9) Value at T = 293 K.
19) Value at T = 310 K.
31) Value at T = 295 K.
89) Measured at high temperature and extrapolated to T = 298.15 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
103) The value is most probably taken from the report by Howe et al. (1987).
116) Value given here as quoted by Staudinger and Roberts (1996).
122) Extrapolated from data above 298 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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