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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Miscellaneous → 2-methoxyethanol

FORMULA:C3H8O2
TRIVIAL NAME: methyl cellosolve
CAS RN:109-86-4
STRUCTURE
(FROM NIST):
InChIKey:XNWFRZJHXBZDAG-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
4.4 7500 Hiatt 2013 M
2.2×10−4 -870 Ashworth et al. 1988 M 103)
1.4×101 Johanson and Dynésius 1988 M 19)
3.7×101 7300 Cabani et al. 1978 T
2.1×101 Hilal et al. 2008 Q
1.5×101 Nirmalakhandan et al. 1997 Q

References

  • Ashworth, R. A., Howe, G. B., Mullins, M. E., and Rogers, T. N.: Air-water partitioning coefficients of organics in dilute aqueous solutions, J. Hazard. Mater., 18, 25-36, doi:10.1016/0304-3894(88)85057-X, 1988.
  • Cabani, S., Mollica, V., and Lepori, L.: Thermodynamic study of dilute aqueous solutions of organic compounds. Part 5. - Open-chain saturated bifunctional compounds, J. Chem. Soc. Faraday Trans. 1, 74, 2667-2671, doi:10.1039/F19787402667, 1978.
  • Hiatt, M. H.: Determination of Henry's law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902-908, doi:10.1021/JE3010535, 2013.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Johanson, G. and Dynésius, B.: Liquid/air partition coefficients of six commonly used glycol ethers, Br. J. Ind. Med., 45, 561-564, doi:10.1136/OEM.45.8.561, 1988.
  • Nirmalakhandan, N., Brennan, R. A., and Speece, R. E.: Predicting Henry's law constant and the effect of temperature on Henry's law constant, Wat. Res., 31, 1471-1481, doi:10.1016/S0043-1354(96)00395-8, 1997.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

19) Value at T = 310 K.
103) The value is most probably taken from the report by Howe et al. (1987).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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