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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Esters (RCOOR) → methyl decanoate

FORMULA:C11H22O2
TRIVIAL NAME: methyl caprate
CAS RN:110-42-9
STRUCTURE
(FROM NIST):
InChIKey:YRHYCMZPEVDGFQ-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.1×10−2 Aprea et al. 2007 M
1.4×10−2 Krop et al. 1997 V
3.2×10−3 Abraham 1984 V
5.8×10−3 HSDB 2015 Q 38)
7.7×10−3 Hilal et al. 2008 Q

References

  • Abraham, M. H.: Thermodynamics of solution of homologous series of solutes in water, J. Chem. Soc. Faraday Trans. 1, 80, 153-181, doi:10.1039/F19848000153, 1984.
  • Aprea, E., Biasioli, F., Märk, T. D., and Gasperi, F.: PTR-MS study of esters in water and water/ethanol solutions: Fragmentation patterns and partition coefficients, Int. J. Mass Spectrom., 262, 114-121, doi:10.1016/J.IJMS.2006.10.016, 2007.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Krop, H. B., van Velzen, M. J. M., Parsons, J. R., and Govers, H. A. J.: n-Octanol-water partition coefficients, aqueous solubilities and Henry's law constants of fatty acid esters, Chemosphere, 34, 107-119, doi:10.1016/S0045-6535(96)00371-2, 1997.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

38) Calculated based on the method by Meylan and Howard (1991).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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