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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) → pentanedioic acid

FORMULA:HOOC(CH2)3COOH
TRIVIAL NAME: glutaric acid
CAS RN:110-94-1
STRUCTURE
(FROM NIST):
InChIKey:JFCQEDHGNNZCLN-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.9×107 Mentel et al. 2004 M
5.1×107 12000 Compernolle and Müller 2014a V
2.4×107 13000 Compernolle and Müller 2014a V
2.2×107 Hilal et al. 2008 Q
2.0×106 Saxena and Hildemann 1996 E 158)

References

  • Compernolle, S. and Müller, J.-F.: Henry's law constants of diacids and hydroxy polyacids: recommended values, Atmos. Chem. Phys., 14, 2699-2712, doi:10.5194/ACP-14-2699-2014, 2014a.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Mentel, T. F., Folkers, M., Tillmann, R., Henk, H., Wahner, A., Otjes, R., Blom, M., and ten Brink, H. M.: Determination of the Henry coefficients for organic aerosol components, Geophys. Res. Abstr., 6, 1525, 2004.
  • Saxena, P. and Hildemann, L. M.: Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds, J. Atmos. Chem., 24, 57-109, doi:10.1007/BF00053823, 1996.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

158) Value obtained by Saxena and Hildemann (1996) using the group contribution method.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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