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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with oxygen (O)Alcohols (ROH) → 1-decanol

FORMULA:C10H22O
CAS RN:112-30-1
STRUCTURE
(FROM NIST):
InChIKey:MWKFXSUHUHTGQN-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
7.6×10−2 6600 Shunthirasingham et al. 2013 M
6.5×10−2 5300 Lei et al. 2007 M 156)
3.1×10−1 Altschuh et al. 1999 M
1.9×10−1 Abraham 1984 V
2.0×10−1 Hilal et al. 2008 Q
2.4×10−1 Nirmalakhandan et al. 1997 Q
2.1×10−1 Yaws et al. 1997 Q
3.7×10−1 Yaws and Yang 1992 ? 92)
1.9×10−1 Abraham et al. 1990 ?

References

  • Abraham, M. H.: Thermodynamics of solution of homologous series of solutes in water, J. Chem. Soc. Faraday Trans. 1, 80, 153-181, doi:10.1039/F19848000153, 1984.
  • Abraham, M. H., Whiting, G. S., Fuchs, R., and Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291-300, doi:10.1039/P29900000291, 1990.
  • Altschuh, J., Brüggemann, R., Santl, H., Eichinger, G., and Piringer, O. G.: Henry's law constants for a diverse set of organic chemicals: Experimental determination and comparison of estimation methods, Chemosphere, 39, 1871-1887, doi:10.1016/S0045-6535(99)00082-X, 1999.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Lei, Y. D., Shunthirasingham, C., and Wania, F.: Comparison of headspace and gas-stripping techniques for measuring the air-water partititioning of normal alkanols (C4 to C10) - effect of temperature, chain length and adsorption to the water surface, J. Chem. Eng. Data, 52, 168-179, doi:10.1021/JE060344Q, 2007.
  • Nirmalakhandan, N., Brennan, R. A., and Speece, R. E.: Predicting Henry's law constant and the effect of temperature on Henry's law constant, Wat. Res., 31, 1471-1481, doi:10.1016/S0043-1354(96)00395-8, 1997.
  • Shunthirasingham, C., Cao, X., Lei, Y. D., and Wania, F.: Larger bubbles reduce the surface sorption artifact during inert gas stripping, J. Chem. Eng. Data, 58, 792-797, doi:10.1021/JE301326T, 2013.
  • Yaws, C. L. and Yang, H.-C.: Henry's law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181-206, Gulf Publishing Company, Houston, TX, 1992.
  • Yaws, C. L., Hopper, J. R., Sheth, S. D., Han, M., and Pike, R. W.: Solubility and Henry's law constant for alcohols in water, Waste Manage., 17, 541-547, doi:10.1016/S0956-053X(97)10057-5, 1997.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
156) Extrapolated from data above 298 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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