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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesNitrogen (N) → nitrogen trioxide

FORMULA:NO3
TRIVIAL NAME: nitrate radical
CAS RN:12033-49-7
STRUCTURE
(FROM NIST):
InChIKey:YPJKMVATUPSWOH-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
3.8×10−4 Sander et al. 2011 L
3.8×10−4 Sander et al. 2006 L
1.8×10−2 Thomas et al. 1998 M
5.9×10−3 Rudich et al. 1996 M 33)
1.2×10−1 1900 Chameides 1986 T
3.4×10−4 2000 Berdnikov and Bazhin 1970 T 11)
Jacob 1986 E 34)
Seinfeld and Pandis 1998 ? 35)

References

  • Berdnikov, V. M. and Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., Engl. Transl., 44, 395-398, 1970.
  • Chameides, W. L.: Reply, J. Geophys. Res., 91D, 14 571-14 572, doi:10.1029/JD091ID13P14571, 1986.
  • Jacob, D. J.: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91D, 9807-9826, doi:10.1029/JD091ID09P09807, 1986.
  • Rudich, Y., Talukdar, R. K., Ravishankara, A. R., and Fox, R. W.: Reactive uptake of NO3 on pure water and ionic solutions, J. Geophys. Res., 101D, 21 023-21 031, doi:10.1029/96JD01844, 1996.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Seinfeld, J. H. and Pandis, S. N.: Atmospheric Chemistry and Physics, John Wiley & Sons, Inc., 1998.
  • Thomas, K., Volz-Thomas, A., Mihelcic, D., Smit, H. G. J., and Kley, D.: On the exchange of NO3 radicals with aqueous solutions: Solubility and sticking coefficient, J. Atmos. Chem., 29, 17-43, doi:10.1023/A:1005860312363, 1998.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

11) Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.
33) Value obtained by estimating the diffusion coefficient for NO3 to be D = 1.0×10−5 cm2/s.
34) Jacob (1986) assume that NO3 has the same Henry's law constant as HNO3.
35) Seinfeld and Pandis (1998) probably refer to the incorrect value given by Pandis and Seinfeld (1989).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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