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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with phosphorus (P)Phosphorus (C, H, O, N, Cl, Br, S, P) → malathion

FORMULA:C10H19O6PS2
CAS RN:121-75-5
STRUCTURE
(FROM NIST):
InChIKey:JXSJBGJIGXNWCI-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
6.7×102 Watanabe 1993 M
2.0×103 Fendinger and Glotfelty 1990 M
4.4×102 Mackay et al. 2006d V
2.5×102 Cotham and Bidleman 1989 V
4.3×102 Suntio et al. 1988 V 9)
1.7×102 Glotfelty et al. 1987 V
7.3×103 Sanders and Seiber 1983 V 31)
2.6×101 Mackay and Shiu 1981 V
1.5×102 Hilal et al. 2008 Q

References

  • Cotham, W. E. and Bidleman, T. F.: Degradation of malathion, endosulfan, and fenvalerate in seawater and seawater/sediment microcosms, J. Agric. Food Chem., 37, 824-828, doi:10.1021/JF00087A055, 1989.
  • Fendinger, N. J. and Glotfelty, D. E.: Henry's law constants for selected pesticides, PAHs and PCBs, Environ. Toxicol. Chem., 9, 731-735, doi:10.1002/ETC.5620090606, 1990.
  • Glotfelty, D. E., Seiber, J. N., and Liljedahl, A.: Pesticides in fog, Nature, 325, 602-605, doi:10.1038/325602A0, 1987.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Mackay, D. and Shiu, W. Y.: A critical review of Henry's law constants for chemicals of environmental interest, J. Phys. Chem. Ref. Data, 10, 1175-1199, doi:10.1063/1.555654, 1981.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Sanders, P. F. and Seiber, J. N.: A chamber for measuring volatilization of pesticides from model soil and water disposal systems, Chemosphere, 12, 999-1012, doi:10.1016/0045-6535(83)90252-7, 1983.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.
  • Watanabe, T.: Relationship between volatilization rates and physicochemical properties of some pesticides, J. Pestic. Sci., 18, 201-209, doi:10.1584/JPESTICS.18.3_201, 1993.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
31) Value at T = 295 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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