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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with oxygen (O)Heterocycles with oxygen → 1,4-dioxane

FORMULA:C4H8O2
TRIVIAL NAME: dioxane
CAS RN:123-91-1
STRUCTURE
(FROM NIST):
InChIKey:RYHBNJHYFVUHQT-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.3 6600 Hiatt 2013 M
1.4 5100 Kolb et al. 1992 M 102)
2.1 Park et al. 1987 M
1.4 Friant and Suffet 1979 M 23)
2.2 Rohrschneider 1973 M
1.9 Hwang et al. 1992 V
1.1 Amoore and Buttery 1978 V
2.0 5800 Cabani et al. 1971b T
3.3 Hilal et al. 2008 Q
5200 Kühne et al. 2005 Q
6100 Kühne et al. 2005 ?
2.0 Betterton 1992 ? 210)
2.2 Betterton 1992 ? 211)
1.4 Yaws and Yang 1992 ? 92)

References

  • Amoore, J. E. and Buttery, R. G.: Partition coefficient and comparative olfactometry, Chem. Senses Flavour, 3, 57-71, doi:10.1093/CHEMSE/3.1.57, 1978.
  • Betterton, E. A.: Henry's law constants of soluble and moderately soluble organic gases: Effects on aqueous phase chemistry, Adv. Environ. Sci. Technol., 24, 1-50, 1992.
  • Cabani, S., Conti, G., and Lepori, L.: Thermodynamic study on aqueous dilute solutions of organic compounds. Part 2. - Cyclic ethers, Trans. Faraday Soc., 67, 1943-1950, doi:10.1039/TF9716701943, 1971b.
  • Friant, S. L. and Suffet, I. H.: Interactive effects of temperature, salt concentration, and pH on head space analysis for isolating volatile trace organics in aqueous environmental samples, Anal. Chem., 51, 2167-2172, doi:10.1021/AC50049A027, 1979.
  • Hiatt, M. H.: Determination of Henry's law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902-908, doi:10.1021/JE3010535, 2013.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Hwang, Y.-L., Olson, J. D., and Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759-1768, doi:10.1021/IE00007A022, 1992.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Kolb, B., Welter, C., and Bichler, C.: Determination of partition coefficients by automatic equilibrium headspace gas chromatography by vapor phase calibration, Chromatographia, 34, 235-240, doi:10.1007/BF02268351, 1992.
  • Park, J. H., Hussam, A., Couasnon, P., Fritz, D., and Carr, P. W.: Experimental reexamination of selected partition coefficients from Rohrschneider's data set, Anal. Chem., 59, 1970-1976, doi:10.1021/AC00142A016, 1987.
  • Rohrschneider, L.: Solvent characterization by gas-liquid partition coefficients of selected solutes, Anal. Chem., 45, 1241-1247, doi:10.1021/AC60329A023, 1973.
  • Yaws, C. L. and Yang, H.-C.: Henry's law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181-206, Gulf Publishing Company, Houston, TX, 1992.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

23) Value at T = 303 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
102) Extrapolated from data measured between 40 °C and 80 °C.
210) Betterton (1992) gives Hine and Weimar (1965) as the source. However, no data were found in that reference.
211) Betterton (1992) gives Vitenberg et al. (1975) as the source. However, no data were found in that reference.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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