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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) → hexanedioic acid

FORMULA:HOOC(CH2)4COOH
TRIVIAL NAME: adipic acid
CAS RN:124-04-9
STRUCTURE
(FROM NIST):
InChIKey:WNLRTRBMVRJNCN-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.1×106 HSDB 2015 V
6.6×107 13000 Compernolle and Müller 2014a V
1.1×101 Lide and Frederikse 1995 V
1.8×105 11000 Goldstein 1982 X 116)
2.5×107 Hilal et al. 2008 Q
2.0×106 Saxena and Hildemann 1996 E 158)

References

  • Compernolle, S. and Müller, J.-F.: Henry's law constants of diacids and hydroxy polyacids: recommended values, Atmos. Chem. Phys., 14, 2699-2712, doi:10.5194/ACP-14-2699-2014, 2014a.
  • Goldstein, D. J.: Air and steam stripping of toxic pollutants, Appendix 3: Henry's law constants, Tech. Rep. EPA-68-03-002, Industrial Environmental Research Laboratory, Cincinnati, OH, USA, 1982.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Lide, D. R. and Frederikse, H. P. R., eds.: CRC Handbook of Chemistry and Physics, 76th Edition, CRC Press, Inc., Boca Raton, FL, 1995.
  • Saxena, P. and Hildemann, L. M.: Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds, J. Atmos. Chem., 24, 57-109, doi:10.1007/BF00053823, 1996.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

116) Value given here as quoted by Staudinger and Roberts (1996).
158) Value obtained by Saxena and Hildemann (1996) using the group contribution method.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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