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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsHydrocarbons (C, H)Terpenes and terpenoids → β-pinene

FORMULA:C10H16
CAS RN:127-91-3
STRUCTURE
(FROM NIST):
InChIKey:WTARULDDTDQWMU-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.6×10−4 Helburn et al. 2008 M
1.5×10−4 4500 Copolovici and Niinemets 2005 M
4.9×10−4 Karl et al. 2003 M 31)
4.7×10−5 Falk et al. 1990 M 19)
1.5×10−4 Copolovici and Niinemets 2005 V
1.5×10−4 Niinemets and Reichstein 2002 V
6.2×10−5 HSDB 2015 Q 38)

References

  • Copolovici, L. O. and Niinemets, U.: Temperature dependencies of Henry's law constants and octanol/water partition coefficients for key plant volatile monoterpenoids, Chemosphere, 61, 1390-1400, doi:10.1016/J.CHEMOSPHERE.2005.05.003, 2005.
  • Falk, A., Gullstrand, E., Löf, A., and Wigaeus-Hjelm, E.: Liquid/air partition coefficients of four terpenes, Br. J. Ind. Med., 47, 62-64, doi:10.1136/OEM.47.1.62, 1990.
  • Helburn, R., Albritton, J., Howe, G., Michael, L., and Franke, D.: Henry's law constants for fragrance and organic solvent compounds in aqueous industrial surfactants, J. Chem. Eng. Data, 53, 1071-1079, doi:10.1021/JE700418A, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Karl, T., Yeretzian, C., Jordan, A., and Lindinger, W.: Dynamic measurements of partition coefficients using proton-transfer-reaction mass spectrometry (PTR-MS), Int. J. Mass Spectrom., 223-224, 383-395, doi:10.1016/S1387-3806(02)00927-2, 2003.
  • Niinemets, U. and Reichstein, M.: A model analysis of the effects of nonspecific monoterpenoid storage in leaf tissues on emission kinetics and composition in Mediterranean sclerophyllous Quercus species, Global Biogeochem. Cycles, 16, 1110, doi:10.1029/2002GB001927, 2002.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

19) Value at T = 310 K.
31) Value at T = 295 K.
38) Calculated based on the method by Meylan and Howard (1991).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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