When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | BrCl |
CAS RN: | 13863-41-7 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | CODNYICXDISAEA-UHFFFAOYSA-N |
Hcp |
d ln Hcp / d (1/T) |
Reference |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
9.7×10−3 |
5600 |
Sander et al. 2011 |
L |
|
9.7×10−3 |
5600 |
Sander et al. 2006 |
L |
|
< 6.2×10−2 |
|
Katrib et al. 2001 |
M |
66)
|
1.5×10−2 |
|
Disselkamp et al. 1999 |
M |
67)
|
9.3×10−3 |
5600 |
Bartlett and Margerum 1999 |
M |
|
4.2×10−2 |
4000 |
Dubik et al. 1987 |
M |
59)
|
1.1×10−2 |
|
|
T |
68)
|
5.8×10−3 |
|
Frenzel et al. 1998 |
E |
|
References
-
Bartlett, W. P. and Margerum, D. W.: Temperature dependencies of the Henry's law constant and the aqueous phase dissociation constant of bromine chloride, Environ. Sci. Technol., 33, 3410-3414, doi:10.1021/ES990300K, 1999.
-
Disselkamp, R. S., Chapman, E. G., Barchet, W. R., Colson, S. D., and Howd, C. D.: BrCl production in NaBr/NaCl/HNO3/O3 solutions representative of sea-salt aerosols in the marine boundary layer, Geophys. Res. Lett., 26, 2183-2186, doi:10.1029/1999GL900251, 1999.
-
Dubik, N. A., Titova, G. M., and Loshakova, E. I.: Partition coefficients of bromine and bromine chloride between air and natural brines, Issled. v Obl. Poluch. Magniya, Ioda, Broma i ikh Soed., M., pp. 53-57, (in Russian, see also Chem. Abstr., 109, 213154j), 1987.
-
Frenzel, A., Scheer, V., Sikorski, R., George, C., Behnke, W., and Zetzsch, C.: Heterogeneous interconversion reactions of BrNO2, ClNO2, Br2, and Cl2, J. Phys. Chem. A, 102, 1329-1337, doi:10.1021/JP973044B, 1998.
-
Katrib, Y., Deiber, G., Schweitzer, F., Mirabel, P., and George, C.: Chemical transformation of bromine chloride at the air/water interface, J. Aerosol Sci., 32, 893-911, doi:10.1016/S0021-8502(00)00114-2, 2001.
-
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
-
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
-
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
59) |
Dubik et al. (1987) measured the solubility in concentrated salt solutions (natural brines). |
66) |
Value at T = 275 K. |
67) |
Value at T = 290 K. |
68) |
Calculated using data from Wagman et al. (1982) and the aqueous-phase equilibrium Cl2 + Br2 ↔ 2 BrCl from Wang et al. (1994). |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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