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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with bromine (Br)Bromine, chlorine and fluorine (C, H, N, O, F, Cl, Br) → 1-bromo-1-chloro-2,2,2-trifluoroethane

FORMULA:C2HBrClF3
TRIVIAL NAME: halothane
CAS RN:151-67-7
STRUCTURE
(FROM NIST):
InChIKey:BCQZXOMGPXTTIC-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.6×10−4 4700 Fogg and Sangster 2003 L
3.1×10−4 Steward et al. 1973 L 19)
2.8×10−4 Guitart et al. 1989 M 19)
3.3×10−4 Lerman et al. 1983 M 19)
5.3×10−4 5000 Smith et al. 1981b M
3.2×10−4 Stoelting and Longshore 1972 M 19)
8.8×10−4 Hilal et al. 2008 Q
4100 Kühne et al. 2005 Q
4.9×10−4 HSDB 2015 ? 170)
5000 Kühne et al. 2005 ?
4.8×10−4 Abraham et al. 1990 ?

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., and Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291-300, doi:10.1039/P29900000291, 1990.
  • Fogg, P. and Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc., 2003.
  • Guitart, R., Puigdemont, F., and Arboix, M.: Rapid headspace gas chromatographic method for the determination of liquid/gas partition coefficients, J. Chromatogr., 491, 271-280, doi:10.1016/S0378-4347(00)82845-5, 1989.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Lerman, J., Willis, M. M., Gregory, G. A., and Eger, E. I.: Osmolarity determines the solubility of anesthetics in aqueous solutions at 37 ° C, Anesthesiology, 59, 554-558, doi:10.1097/00000542-198312000-00013, 1983.
  • Smith, R. A., Porter, E. G., and Miller, K. W.: The solubility of anesthetic gases in lipid bilayers, Biochim. Biophys. Acta - Biomembranes, 645, 327-338, 1981b.
  • Steward, A., Allott, P. R., Cowles, A. L., and Mapleson, W. W.: Solubility coefficients for inhaled anaesthetics for water, oil and biological media, Br. J. Anaesth., 45, 282-293, doi:10.1093/BJA/45.3.282, 1973.
  • Stoelting, R. K. and Longshore, R. E.: The effects of temperature on fluroxene, halothane, and methoxyflurane blood-gas and cerebrospinal fluid-gas partition coefficients, Anesthesiology, 36, 503-505, doi:10.1097/00000542-197205000-00018, 1972.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

19) Value at T = 310 K.
170) HSDB (2015) refer to Abraham et al. (1994b) as the source but this value cannot be found there. Maybe the value is taken from Abraham et al. (1990).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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