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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with oxygen (O)Peroxides (ROOH) and peroxy radicals (ROO) → hydroxymethyl hydroperoxide

FORMULA:HOCH2OOH
TRIVIAL NAME: HMHP; HMP
CAS RN:15932-89-5
STRUCTURE
(FROM NIST):
InChIKey:NEZWFWIACBUQMN-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.7×104 9900 Sander et al. 2011 L
1.7×104 9900 Sander et al. 2006 L
1.6×104 10000 Staudinger and Roberts 2001 L
1.6×104 9700 O'Sullivan et al. 1996 M
1.6×104 10000 Staffelbach and Kok 1993 M
4.7×103 1500 Zhou and Lee 1992 M
8600 Kühne et al. 2005 Q
10000 Kühne et al. 2005 ?

References

  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • O'Sullivan, D. W., Lee, M., Noone, B. C., and Heikes, B. G.: Henry's law constant determinations for hydrogen peroxide, methyl hydroperoxide, hydroxymethyl hydroperoxide, ethyl hydroperoxide, and peroxyacetic acid, J. Phys. Chem., 100, 3241-3247, doi:10.1021/JP951168N, 1996.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Staffelbach, T. A. and Kok, G. L.: Henry's law constants for aqueous solutions of hydrogen peroxide and hydroxymethyl hydroperoxide, J. Geophys. Res., 98D, 12 713-12 717, doi:10.1029/93JD01022, 1993.
  • Staudinger, J. and Roberts, P. V.: A critical compilation of Henry's law constant temperature dependence relations for organic compounds in dilute aqueous solutions, Chemosphere, 44, 561-576, doi:10.1016/S0045-6535(00)00505-1, 2001.
  • Zhou, X. and Lee, Y.-N.: Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide, J. Phys. Chem., 96, 265-272, doi:10.1021/J100180A051, 1992.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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