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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Peroxides (ROOH) and peroxy radicals (ROO) → bis-(hydroxymethyl)-peroxide

FORMULA:HOCH2OOCH2OH
TRIVIAL NAME: BHMP
CAS RN:17088-73-2
STRUCTURE
(FROM NIST):
InChIKey:JLJXMZMKMRQOLN-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
> 9.9×104 Staffelbach and Kok 1993 M
4.4×103 8400 Zhou and Lee 1992 M
9400 Kühne et al. 2005 Q
8500 Kühne et al. 2005 ?

References

  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Staffelbach, T. A. and Kok, G. L.: Henry's law constants for aqueous solutions of hydrogen peroxide and hydroxymethyl hydroperoxide, J. Geophys. Res., 98D, 12 713-12 717, doi:10.1029/93JD01022, 1993.
  • Zhou, X. and Lee, Y.-N.: Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide, J. Phys. Chem., 96, 265-272, doi:10.1021/J100180A051, 1992.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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