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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Peroxides (ROOH) and peroxy radicals (ROO) → methylperoxy radical

FORMULA:CH3OO
CAS RN:2143-58-0
STRUCTURE
(FROM NIST):
InChIKey:WTFNSXYULBQCQV-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.5×10−1 3700 Leriche et al. 2000 E 184)
Lelieveld and Crutzen 1991 E 185)
5.9×10−2 5600 Jacob 1986 E 186)

References

  • Jacob, D. J.: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91D, 9807-9826, doi:10.1029/JD091ID09P09807, 1986.
  • Lelieveld, J. and Crutzen, P. J.: The role of clouds in tropospheric photochemistry, J. Atmos. Chem., 12, 229-267, doi:10.1007/BF00048075, 1991.
  • Leriche, M., Voisin, D., Chaumerliac, N., Monod, A., and Aumont, B.: A model for tropospheric multiphase chemistry: application to one cloudy event during the CIME experiment, Atmos. Environ., 34, 5015-5036, doi:10.1016/S1352-2310(00)00329-0, 2000.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

184) Leriche et al. (2000) assume H(ROO) = H(ROOH) ×H(HO2) / H(H2O2).
185) Lelieveld and Crutzen (1991) assume H(CH3OO) = H(HO2).
186) Jacob (1986) assumes H(CH3OO) = H(CH3OOH) ×H(HO2) / H(H2O2).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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