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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with nitrogen (N)Nitrates (RONO2) → peroxyacetyl nitrate

FORMULA:CH3COOONO2
TRIVIAL NAME: PAN
CAS RN:2278-22-0
STRUCTURE
(FROM NIST):
InChIKey:VGQXTTSVLMQFHM-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.9×10−2 5700 Warneck and Williams 2012 L
2.8×10−2 5700 Sander et al. 2011 L
2.8×10−2 5700 Sander et al. 2006 L
2.9×10−2 5800 Leu and Zhang 1999 L
4.0×10−2 Kames and Schurath 1995 M 9)
2.8×10−2 6500 Kames et al. 1991 M
4.9×10−2 Holdren et al. 1984 M 147)
3.6×10−2 Gaffney and Senum 1984 X 153)
2.9×10−2 5900 Pandis and Seinfeld 1989 C
3.6×10−2 Schwartz 1986 C 31)
2.2 Hilal et al. 2008 Q
4800 Kühne et al. 2005 Q
6300 Kühne et al. 2005 ?
Warneck et al. 1996 ? 227)
Schurath et al. 1996 W 228)

References

  • Gaffney, J. S. and Senum, G. I.: Peroxides, peracids, aldehydes, and PANs and their links to natural and anthropogenic organic sources, in: Gas-Liquid Chemistry of Natural Waters, edited by Newman, L., pp. 5-1-5-7, NTIS TIC-4500, UC-11, BNL 51757 Brookhaven National Laboratory, 1984.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Holdren, M. W., Spicer, C. W., and Hales, J. M.: Peroxyacetyl nitrate solubility and decomposition rate in acidic water, Atmos. Environ., 18, 1171-1173, doi:10.1016/0004-6981(84)90148-3, 1984.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Kames, J. and Schurath, U.: Henry's law and hydrolysis-rate constants for peroxyacyl nitrates (PANs) using a homogeneous gas-phase source, J. Atmos. Chem., 21, 151-164, doi:10.1007/BF00696578, 1995.
  • Kames, J., Schweighoefer, S., and Schurath, U.: Henry's law constant and hydrolysis of peroxyacetyl nitrate (PAN), J. Atmos. Chem., 12, 169-180, doi:10.1007/BF00115778, 1991.
  • Leu, M.-T. and Zhang, R.: Solubilities of CH3C(O)O2NO2 and HO2NO2 in water and liquid H2SO4, Geophys. Res. Lett., 26, 1129-1132, doi:10.1029/1999GL900158, 1999.
  • Pandis, S. N. and Seinfeld, J. H.: Sensitivity analysis of a chemical mechanism for aqueous-phase atmospheric chemistry, J. Geophys. Res., 94D, 1105-1126, doi:10.1029/JD094ID01P01105, 1989.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Schurath, U., Bongartz, A., Kames, J., Wunderlich, C., and Carstens, T.: Chapter 6.4: Laboratory determination of physico-chemical rate parameters pertinent to mass transfer into cloud and fog droplets, in: Heterogeneous and Liquid-Phase Processes, edited by Warneck, P., pp. 182-189, Springer Verlag, Berlin, doi:10.1007/978-3-642-61445-3_6, 1996.
  • Schwartz, S. E.: Mass-transport considerations pertinent to aqueous phase reactions of gases in liquid-water clouds, in: Chemistry of Multiphase Atmospheric Systems, NATO ASI Series, Vol. G6, edited by Jaeschke, W., pp. 415-471, Springer Verlag, Berlin, doi:10.1007/978-3-642-70627-1_16, 1986.
  • Warneck, P. and Williams, J.: The Atmospheric Chemist's Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0, 2012.
  • Warneck, P., Mirabel, P., Salmon, G. A., van Eldik, R., Vinckier, C., Wannowius, K. J., and Zetzsch, C.: Chapter 2: Review of the activities and achievements of the EUROTRAC subproject HALIPP, in: Heterogeneous and Liquid-Phase Processes, edited by Warneck, P., pp. 7-74, Springer Verlag, Berlin, doi:10.1007/978-3-642-61445-3_2, 1996.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
31) Value at T = 295 K.
147) Value at T = 283 K.
153) Value given here as quoted by Gaffney et al. (1987).
227) Comparing the value with that from the cited publication (Kames and Schurath 1995), it can be seen that the unit and the temperature listed in Table 3 of Warneck et al. (1996) are incorrect.
228) The data from Kames and Schurath (1995) for peroxyacetyl nitrate are incorrectly cited by Schurath et al. (1996).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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