When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | C12H6Cl4 |
TRIVIAL NAME:
|
PCB-47
|
CAS RN: | 2437-79-8 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | QORAVNMWUNPXAO-UHFFFAOYSA-N |
Hcp |
d ln Hcp / d (1/T) |
Reference |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
2.1×10−1 |
|
Lau et al. 2006 |
M |
262)
|
9.1×10−3 |
|
Lau et al. 2006 |
M |
263)
|
1.8×10−1 |
-6000 |
Charles and Destaillats 2005 |
M |
|
5.2×10−2 |
|
Brunner et al. 1990 |
M |
|
2.0×10−2 |
6200 |
Paasivirta and Sinkkonen 2009 |
V |
|
5.7×10−2 |
|
Mackay et al. 2006b |
V |
|
5.8×10−2 |
|
Mackay et al. 1992a |
V |
|
2.0×10−3 |
|
Hwang et al. 1992 |
V |
|
5.9×10−2 |
|
Shiu and Mackay 1986 |
V |
|
2.3×10−2 |
|
Burkhard et al. 1985 |
V |
|
5.0×10−2 |
|
Hilal et al. 2008 |
Q |
|
3.5×10−2 |
|
Fang Lee 2007 |
Q |
264)
|
4.8×10−2 |
|
Fang Lee 2007 |
Q |
265)
|
2.7×10−2 |
|
Dunnivant et al. 1992 |
Q |
|
2.2×10−2 |
|
Sabljić and Güsten 1989 |
Q |
|
References
-
Brunner, S., Hornung, E., Santl, H., Wolff, E., Piringer, O. G., Altschuh, J., and Brüggemann, R.: Henry's law constants for polychlorinated biphenyls: Experimental determination and structure-property relationships, Environ. Sci. Technol., 24, 1751-1754, doi:10.1021/ES00081A021, 1990.
-
Burkhard, L. P., Armstrong, D. E., and Andren, A. W.: Henry's law constants for the polychlorinated biphenyls, Environ. Sci. Technol., 19, 590-596, doi:10.1021/ES00137A002, 1985.
-
Charles, M. J. and Destaillats, H.: Experimental determinations of Henry's law constants of polybrominated diphenyl ethers (PBDEs) to evaluate exposure to aquatic biota, technical Completion Report, University of California Water Resources Center, UC Berkeley, http://escholarship.org/uc/item/9zv0s4np, 2005.
-
Dunnivant, F. M., Elzerman, A. W., Jurs, P. C., and Hasan, M. N.: Quantitative structure-property relationships for aqueous solubilities and Henry's law constants of polychlorinated biphenyls, Environ. Sci. Technol., 26, 1567-1573, doi:10.1021/ES00032A012, 1992.
-
Fang Lee, F.: Comprehensive analysis, Henry's law constant determination, and photocatalytic degradation of polychlorinated biphenyls (PCBs) and/or other persistent organic pollutants (POPs), Ph.D. thesis, University at Albany, State University of New York, USA, 2007.
-
Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
-
Hwang, Y.-L., Olson, J. D., and Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759-1768, doi:10.1021/IE00007A022, 1992.
-
Lau, F. K., Charles, M. J., and Cahill, T. M.: Evaluation of gas-stripping methods for the determination of Henry's law constants for polybrominated diphenyl ethers and polychlorinated biphenyls, J. Chem. Eng. Data, 51, 871-878, doi:10.1021/JE050308B, 2006.
-
Mackay, D., Shiu, W. Y., and Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. I of Monoaromatic Hydrocarbons, Chlorobenzenes, and PCBs , Lewis Publishers, Boca Raton, 1992a.
-
Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. II of Halogenated Hydrocarbons , CRC/Taylor & Francis Group, 2006b.
-
Paasivirta, J. and Sinkkonen, S. I.: Environmentally relevant properties of all 209 polychlorinated biphenyl congeners for modeling their fate in different natural and climatic conditions, J. Chem. Eng. Data, 54, 1189-1213, doi:10.1021/JE800501H, 2009.
-
Sabljić, A. and Güsten, H.: Predicting Henry's law constants for polychlorinated biphenyls, Chemosphere, 19, 1503-1511, doi:10.1016/0045-6535(89)90495-5, 1989.
-
Shiu, W. Y. and Mackay, D.: A critical review of aqueous solubilities, vapor pressures, Henry's law constants, and octanol-water partition coefficients of the polychlorinated biphenyls, J. Phys. Chem. Ref. Data, 15, 911-929, doi:10.1063/1.555755, 1986.
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
262) |
Modified gas-stripping method (MGSM), see Lau et al. (2006) for details. |
263) |
Integrated gas-stripping method (IGSM), see Lau et al. (2006) for details. |
264) |
Calculated with the principal component regression (PCR) method, see Fang Lee (2007) for details. |
265) |
Calculated with the partial least-square regression (PLSR) method, see Fang Lee (2007) for details. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
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