MPG

Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Home

Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with phosphorus (P)Phosphorus (C, H, O, N, Cl, Br, S, P) → chlorpyrifos

FORMULA:C9H11Cl3NO3PS
CAS RN:2921-88-2
STRUCTURE
(FROM NIST):
InChIKey:SBPBAQFWLVIOKP-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.8 Muir et al. 2004 L 144)
2.1 Muir et al. 2004 L 143)
2.2×10−1 7800 Cetin et al. 2006 M
3.1 Rice et al. 1997b M 9)
2.4 Fendinger and Glotfelty 1990 M
9.2×10−1 Mackay et al. 2006d V
1.7 Siebers et al. 1994 V
5.7×10−1 Suntio et al. 1988 V 9)
8.1×10−1 Glotfelty et al. 1987 V
3.4 HSDB 2015 C
1.4 Armbrust 2000 C
2.2×10−1 Hilal et al. 2008 Q
2.5×102 Meylan and Howard 1991 Q

References

  • Armbrust, K. L.: Pesticide hydroxyl radical rate constants: Measurements and estimates of their importance in aquatic environments, Environ. Toxicol. Chem., 19, 2175-2180, doi:10.1897/1551-5028(2000)019<2175:PHRRCM>2.3.CO;2, 2000.
  • Cetin, B., Ozer, S., Sofuoglu, A., and Odabasi, M.: Determination of Henry's law constants of organochlorine pesticides in deionized and saline water as a function of temperature, Atmos. Environ., 40, 4538-4546, doi:10.1016/J.ATMOSENV.2006.04.009, 2006.
  • Fendinger, N. J. and Glotfelty, D. E.: Henry's law constants for selected pesticides, PAHs and PCBs, Environ. Toxicol. Chem., 9, 731-735, doi:10.1002/ETC.5620090606, 1990.
  • Glotfelty, D. E., Seiber, J. N., and Liljedahl, A.: Pesticides in fog, Nature, 325, 602-605, doi:10.1038/325602A0, 1987.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Meylan, W. M. and Howard, P. H.: Bond contribution method for estimating Henry's law constants, Environ. Toxicol. Chem., 10, 1283-1293, doi:10.1002/ETC.5620101007, 1991.
  • Muir, D. C. G., Teixeira, C., and Wania, F.: Empirical and modeling evidence of regional atmospheric transport of current-use pesticides, Environ. Toxicol. Chem., 23, 2421-2432, doi:10.1897/03-457, 2004.
  • Rice, C. P., Chernyak, S. M., and McConnell, L. L.: Henry's law constants for pesticides measured as a function of temperature and salinity, J. Agric. Food Chem., 45, 2291-2298, doi:10.1021/JF960834U, 1997b.
  • Siebers, J., Gottschild, D., and Nolting, H.-G.: Pesticides in precipitation in northern Germany, Chemosphere, 28, 1559-1570, doi:10.1016/0045-6535(94)90249-6, 1994.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
143) Literature-derived value.
144) Final adjusted value.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

* * *

Search Henry's Law Database

Species Search:

Identifier Search:

Reference Search:

* * *

Convert Henry's Law Constants

Convert:

* * *