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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with phosphorus (P)Phosphorus (C, H, O, N, Cl, Br, S, P) → methylparathion

FORMULA:C8H10NO5PS
CAS RN:298-00-0
STRUCTURE
(FROM NIST):
InChIKey:RLBIQVVOMOPOHC-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.0×101 Mackay and Shiu 1981 L
2.6×102 Rice et al. 1997b M 9)
1.6×102 Fendinger and Glotfelty 1990 M
9.9×101 Metcalfe et al. 1980 M
4.7×101 Mackay et al. 2006d V
9.9×101 Woodrow et al. 1990 V
4.7×101 Suntio et al. 1988 V 9)
9.2×101 Glotfelty et al. 1987 V
2.1×103 Sanders and Seiber 1983 V 31)
1.6×102 Metcalfe et al. 1980 V
1.5×101 Hilal et al. 2008 Q

References

  • Fendinger, N. J. and Glotfelty, D. E.: Henry's law constants for selected pesticides, PAHs and PCBs, Environ. Toxicol. Chem., 9, 731-735, doi:10.1002/ETC.5620090606, 1990.
  • Glotfelty, D. E., Seiber, J. N., and Liljedahl, A.: Pesticides in fog, Nature, 325, 602-605, doi:10.1038/325602A0, 1987.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Mackay, D. and Shiu, W. Y.: A critical review of Henry's law constants for chemicals of environmental interest, J. Phys. Chem. Ref. Data, 10, 1175-1199, doi:10.1063/1.555654, 1981.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Metcalfe, C. D., McLeese, D. W., and Zitko, V.: Rate of volatilization of fenitrothion from fresh water, Chemosphere, 9, 151-155, doi:10.1016/0045-6535(80)90086-7, 1980.
  • Rice, C. P., Chernyak, S. M., and McConnell, L. L.: Henry's law constants for pesticides measured as a function of temperature and salinity, J. Agric. Food Chem., 45, 2291-2298, doi:10.1021/JF960834U, 1997b.
  • Sanders, P. F. and Seiber, J. N.: A chamber for measuring volatilization of pesticides from model soil and water disposal systems, Chemosphere, 12, 999-1012, doi:10.1016/0045-6535(83)90252-7, 1983.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.
  • Woodrow, J. E., McChesney, M. M., and Seiber, J. N.: Modeling the volatilization of pesticides and their distribution in the atmosphere, in: Long Range Transport of Pesticides, edited by Kurtz, D. A., pp. 61-81, CRC Press, 1990.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
31) Value at T = 295 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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