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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with oxygen (O)Peroxides (ROOH) and peroxy radicals (ROO) → ethyl hydroperoxide

FORMULA:C2H5OOH
TRIVIAL NAME: ethyl peroxide
CAS RN:3031-74-1
STRUCTURE
(FROM NIST):
InChIKey:ILHIHKRJJMKBEE-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
3.3 6000 Sander et al. 2011 L
1.1×101 Sauer 1997 M 183)
3.3 6000 O'Sullivan et al. 1996 M
5.8×10−1 Hilal et al. 2008 Q
6600 Kühne et al. 2005 Q
6000 Kühne et al. 2005 ?

References

  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • O'Sullivan, D. W., Lee, M., Noone, B. C., and Heikes, B. G.: Henry's law constant determinations for hydrogen peroxide, methyl hydroperoxide, hydroxymethyl hydroperoxide, ethyl hydroperoxide, and peroxyacetic acid, J. Phys. Chem., 100, 3241-3247, doi:10.1021/JP951168N, 1996.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Sauer, F.: Bestimmung von H2O2 und organischen Peroxiden in Labor- und Feldmessungen mittels Umkehrphasen-Hochdruck-Flüssigkeitschromatographie und enzymatischer Nachsäulenderivatisierung, Ph.D. thesis, Johannes Gutenberg-Universität, Mainz, Germany, 1997.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

183) Value at T = 278 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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