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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorofluorocarbons (C, H, O, N, F, Cl) → 2,2-dichloro-1,1,1-trifluoroethane

FORMULA:C2HF3Cl2
TRIVIAL NAME: R123
CAS RN:306-83-2
STRUCTURE
(FROM NIST):
InChIKey:OHMHBGPWCHTMQE-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.3×10−4 2400 Kutsuna 2013 M
3.3×10−4 3400 Chang and Criddle 1995 M
2.8×10−4 2600 McLinden 1989 V
5.0×10−4 Hilal et al. 2008 Q

References

  • Chang, W.-K. and Criddle, C. S.: Biotransformation of HCFC-22, HCFC-142b, HCFC-123, and HFC-134a by methanotrophic mixed culture MM1, Biodegrad., 6, 1-9, doi:10.1007/BF00702293, 1995.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Kutsuna, S.: Determination of rate constants for aqueous reactions of HCFC-123 and HCFC-225ca with OH along with Henry's law constants of several HCFCs, Int. J. Chem. Kinetics, 45, 440-451, doi:10.1002/KIN.20780, 2013.
  • McLinden, M. O.: Physical properties of alternatives to the fully halogenated chlorofluorocarbons, in: WMO Report 20, Scientific Assessment of Stratospheric Ozone: 1989, Volume II, pp. 11-38, World Meteorol. Organ., Geneva, 1989.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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