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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesHydrogen (H) → hydroperoxy radical

FORMULA:HO2
CAS RN:3170-83-0
STRUCTURE
(FROM NIST):
InChIKey:MHAJPDPJQMAIIY-UHFFFAOYSA-M

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
6.8 Sander et al. 2011 L
6.8 Sander et al. 2006 L
5.7×101 Régimbal and Mozurkewich 1997 R
3.8×101 5900 Hanson et al. 1992 T
8.9×101 Weinstein-Lloyd and Schwartz 1991 T
8.9×101 Chameides 1984 T
1.2×101 Schwartz 1984 T 13)
4.6×101 4800 Berdnikov and Bazhin 1970 T 11)
6600 Jacob 1986 E 14)

References

  • Berdnikov, V. M. and Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., Engl. Transl., 44, 395-398, 1970.
  • Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89D, 4739-4755, doi:10.1029/JD089ID03P04739, 1984.
  • Hanson, D. R., Burkholder, J. B., Howard, C. J., and Ravishankara, A. R.: Measurement of OH and HO2 radical uptake coefficients on water and sulfuric acid surfaces, J. Phys. Chem., 96, 4979-4985, doi:10.1021/J100191A046, 1992.
  • Jacob, D. J.: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91D, 9807-9826, doi:10.1029/JD091ID09P09807, 1986.
  • Régimbal, J.-M. and Mozurkewich, M.: Peroxynitric acid decay mechanisms and kinetics at low pH, J. Phys. Chem. A, 101, 8822-8829, doi:10.1021/JP971908N, 1997.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Schwartz, S. E.: Gas- and aqueous-phase chemistry of HO2 in liquid water clouds, J. Geophys. Res., 89D, 11 589-11 598, doi:10.1029/JD089ID07P11589, 1984.
  • Weinstein-Lloyd, J. and Schwartz, S. E.: Low-intensity radiolysis study of free-radical reactions in cloudwater: H2O2 production and destruction, Environ. Sci. Technol., 25, 791-800, doi:10.1021/ES00016A027, 1991.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

11) Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.
13) In the abstract, Schwartz (1984) gives a range of 9.9 mol/(m3 Pa) < Hcp < 3.0×101 mol/(m3 Pa). The mean value of this range (2.0×101 mol/(m3 Pa)) has been used by Lelieveld and Crutzen (1991), Pandis and Seinfeld (1989), and Jacob (1986).
14) The value of H was taken from Schwartz (1984).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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