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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with phosphorus (P)Phosphorus (C, H, O, N, Cl, Br, S, P) → diazinon

FORMULA:C12H21N2O3PS
TRIVIAL NAME: dimpylate
CAS RN:333-41-5
STRUCTURE
(FROM NIST):
InChIKey:FHIVAFMUCKRCQO-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
4.6×101 Muir et al. 2004 L 144)
9.2×101 Muir et al. 2004 L 143)
1.5×101 12000 Feigenbrugel et al. 2004a M
1.1×101 Watanabe 1993 M
8.4×101 Fendinger et al. 1989 M 126)
8.8×101 Fendinger and Glotfelty 1988 M 126)
2.5×101 Mackay et al. 2006d V
1.5×101 Suntio et al. 1988 V 9)
6.7 Glotfelty et al. 1987 V
1.0×102 Sanders and Seiber 1983 V 31)
1.3×101 Burkhard and Guth 1981 V
1.4×102 Meylan and Howard 1991 Q

References

  • Burkhard, N. and Guth, J. A.: Rate of volatilisation of pesticides from soil surfaces; comparison of calculated results with those determined in a laboratory model system, Pestic. Sci., 12, 37-44, doi:10.1002/PS.2780120106, 1981.
  • Feigenbrugel, V., Le Calvé, S., and Mirabel, P.: Temperature dependence of Henry's law constants of metolachlor and diazinon, Chemosphere, 57, 319-327, doi:10.1016/J.CHEMOSPHERE.2004.05.013, 2004a.
  • Fendinger, N. J. and Glotfelty, D. E.: A laboratory method for the experimental determination of air-water Henry's law constants for several pesticides, Environ. Sci. Technol., 22, 1289-1293, doi:10.1021/ES00176A007, 1988.
  • Fendinger, N. J., Glotfelty, D. E., and Freeman, H. P.: Comparison of two experimental techniques for determining air/water Henry's law constants, Environ. Sci. Technol., 23, 1528-1531, doi:10.1021/ES00070A013, 1989.
  • Glotfelty, D. E., Seiber, J. N., and Liljedahl, A.: Pesticides in fog, Nature, 325, 602-605, doi:10.1038/325602A0, 1987.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Meylan, W. M. and Howard, P. H.: Bond contribution method for estimating Henry's law constants, Environ. Toxicol. Chem., 10, 1283-1293, doi:10.1002/ETC.5620101007, 1991.
  • Muir, D. C. G., Teixeira, C., and Wania, F.: Empirical and modeling evidence of regional atmospheric transport of current-use pesticides, Environ. Toxicol. Chem., 23, 2421-2432, doi:10.1897/03-457, 2004.
  • Sanders, P. F. and Seiber, J. N.: A chamber for measuring volatilization of pesticides from model soil and water disposal systems, Chemosphere, 12, 999-1012, doi:10.1016/0045-6535(83)90252-7, 1983.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.
  • Watanabe, T.: Relationship between volatilization rates and physicochemical properties of some pesticides, J. Pestic. Sci., 18, 201-209, doi:10.1584/JPESTICS.18.3_201, 1993.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
31) Value at T = 295 K.
126) Value at T = 296 K.
143) Literature-derived value.
144) Final adjusted value.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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