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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesHydrogen (H) → hydroxyl radical

FORMULA:OH
CAS RN:3352-57-6
STRUCTURE
(FROM NIST):
InChIKey:TUJKJAMUKRIRHC-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
3.8×10−1 Sander et al. 2011 L
3.8×10−1 Sander et al. 2006 L
2.9×10−1 4300 Hanson et al. 1992 T
3.2×10−1 Mozurkewich 1986 T
2.9×10−1 3100 Berdnikov and Bazhin 1970 T 11)
2.5×10−1 Lelieveld and Crutzen 1991 C
2.0 Lelieveld and Crutzen 1991 C
8.9×101 Lelieveld and Crutzen 1991 C
2.5×10−1 5300 Jacob 1986 C 12)

References

  • Berdnikov, V. M. and Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., Engl. Transl., 44, 395-398, 1970.
  • Hanson, D. R., Burkholder, J. B., Howard, C. J., and Ravishankara, A. R.: Measurement of OH and HO2 radical uptake coefficients on water and sulfuric acid surfaces, J. Phys. Chem., 96, 4979-4985, doi:10.1021/J100191A046, 1992.
  • Jacob, D. J.: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91D, 9807-9826, doi:10.1029/JD091ID09P09807, 1986.
  • Lelieveld, J. and Crutzen, P. J.: The role of clouds in tropospheric photochemistry, J. Atmos. Chem., 12, 229-267, doi:10.1007/BF00048075, 1991.
  • Mozurkewich, M.: Comment on "Possible role of NO3 in the nighttime chemistry of a cloud" by William L. Chameides, J. Geophys. Res., 91D, 14 569-14 570, doi:10.1029/JD091ID13P14569, 1986.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

11) Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.
12) Jacob (1986) assumed the temperature dependence to be the same as for water.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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