When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | C12H7Cl3 |
TRIVIAL NAME:
|
PCB-22
|
CAS RN: | 38444-85-8 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | ZMHWQAHZKUPENF-UHFFFAOYSA-N |
Hcp |
d ln Hcp / d (1/T) |
Reference |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
3.4×10−2 |
4800 |
Bamford et al. 2002 |
M |
|
5.0×10−2 |
|
Murphy et al. 1987 |
M |
9)
|
1.3×10−2 |
5600 |
Paasivirta and Sinkkonen 2009 |
V |
|
6.5×10−2 |
|
Burkhard et al. 1985 |
V |
|
1.2×10−1 |
|
Hilal et al. 2008 |
Q |
|
3.8×10−2 |
|
Fang Lee 2007 |
Q |
264)
|
6.4×10−2 |
|
Fang Lee 2007 |
Q |
265)
|
5.2×10−2 |
|
Dunnivant et al. 1992 |
Q |
|
4.4×10−2 |
|
Sabljić and Güsten 1989 |
Q |
|
References
-
Bamford, H. A., Poster, D. L., Huie, R. E., and Baker, J. E.: Using extrathermodynamic relationships to model the temperature dependence of Henry's law constants of 209 PCB congeners, Environ. Sci. Technol., 36, 4395-4402, doi:10.1021/ES020599Y, 2002.
-
Burkhard, L. P., Armstrong, D. E., and Andren, A. W.: Henry's law constants for the polychlorinated biphenyls, Environ. Sci. Technol., 19, 590-596, doi:10.1021/ES00137A002, 1985.
-
Dunnivant, F. M., Elzerman, A. W., Jurs, P. C., and Hasan, M. N.: Quantitative structure-property relationships for aqueous solubilities and Henry's law constants of polychlorinated biphenyls, Environ. Sci. Technol., 26, 1567-1573, doi:10.1021/ES00032A012, 1992.
-
Fang Lee, F.: Comprehensive analysis, Henry's law constant determination, and photocatalytic degradation of polychlorinated biphenyls (PCBs) and/or other persistent organic pollutants (POPs), Ph.D. thesis, University at Albany, State University of New York, USA, 2007.
-
Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
-
Murphy, T. J., Mullin, M. D., and Meyer, J. A.: Equilibration of polychlorinated biphenyls and toxaphene with air and water, Environ. Sci. Technol., 21, 155-162, doi:10.1021/ES00156A005, 1987.
-
Paasivirta, J. and Sinkkonen, S. I.: Environmentally relevant properties of all 209 polychlorinated biphenyl congeners for modeling their fate in different natural and climatic conditions, J. Chem. Eng. Data, 54, 1189-1213, doi:10.1021/JE800501H, 2009.
-
Sabljić, A. and Güsten, H.: Predicting Henry's law constants for polychlorinated biphenyls, Chemosphere, 19, 1503-1511, doi:10.1016/0045-6535(89)90495-5, 1989.
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
9) |
Value at T = 293 K. |
264) |
Calculated with the principal component regression (PCR) method, see Fang Lee (2007) for details. |
265) |
Calculated with the partial least-square regression (PLSR) method, see Fang Lee (2007) for details. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
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