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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with fluorine (F)Organic fluorine → (2,2,2-trifluoroethoxy)-ethene

FORMULA:CF3CH2OCHCH2
TRIVIAL NAME: fluoroxene
CAS RN:406-90-6
STRUCTURE
(FROM NIST):
InChIKey:DLEGDLSLRSOURQ-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.4×10−4 4000 Fogg and Sangster 2003 L
3.3×10−4 Steward et al. 1973 L 19)
5.5×10−4 4300 Smith et al. 1981b M
3.2×10−4 Stoelting and Longshore 1972 M 19)
3.3×10−4 Munson et al. 1964 M 19)
9.5×10−5 Hilal et al. 2008 Q
5.1×10−4 Abraham et al. 1990 ?

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., and Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291-300, doi:10.1039/P29900000291, 1990.
  • Fogg, P. and Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc., 2003.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Munson, E. S., Saidman, L. J., and Eger, E. I.: Solubility of fluroxene in blood and tissue homogenates, Anesthesiology, 25, 638-640, doi:10.1097/00000542-196409000-00010, 1964.
  • Smith, R. A., Porter, E. G., and Miller, K. W.: The solubility of anesthetic gases in lipid bilayers, Biochim. Biophys. Acta - Biomembranes, 645, 327-338, 1981b.
  • Steward, A., Allott, P. R., Cowles, A. L., and Mapleson, W. W.: Solubility coefficients for inhaled anaesthetics for water, oil and biological media, Br. J. Anaesth., 45, 282-293, doi:10.1093/BJA/45.3.282, 1973.
  • Stoelting, R. K. and Longshore, R. E.: The effects of temperature on fluroxene, halothane, and methoxyflurane blood-gas and cerebrospinal fluid-gas partition coefficients, Anesthesiology, 36, 503-505, doi:10.1097/00000542-197205000-00018, 1972.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

19) Value at T = 310 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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