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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with fluorine (F)Organic fluorine → 2,2,3,3,3-pentafluoro-1-propanol

FORMULA:CF3CF2CH2OH
CAS RN:422-05-9
STRUCTURE
(FROM NIST):
InChIKey:PSQZJKGXDGNDFP-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.4×10−1 4300 Sander et al. 2011 L
1.4×10−1 4300 Chen et al. 2003 M
4.5×10−1 6000 Rochester and Symonds 1973 M
2.3×10−1 Hilal et al. 2008 Q
6800 Kühne et al. 2005 Q
6000 Kühne et al. 2005 ?

References

  • Chen, L., Takenaka, N., Bandow, H., and Maeda, Y.: Henry's law constants for C2-C3 fluorinated alcohols and their wet deposition in the atmosphere, Atmos. Environ., 37, 4817-4822, doi:10.1016/J.ATMOSENV.2003.08.002, 2003.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Rochester, H. and Symonds, J. R.: Thermodynamic studies of fluoroalcohols. Part 3. - The thermodynamics of transfer of five fluoroalcohols from the gas-phase to aqueous solution, J. Chem. Soc. Faraday Trans. 1, 69, 1577-1585, doi:10.1039/F19736901577, 1973.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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