When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | OCS |
TRIVIAL NAME:
|
carbonyl sulfide
|
CAS RN: | 463-58-1 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | JJWKPURADFRFRB-UHFFFAOYSA-N |
Hcp |
d ln Hcp / d (1/T) |
Reference |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
2.1×10−4 |
3300 |
Warneck and Williams 2012 |
L |
|
2.0×10−4 |
3500 |
Sander et al. 2011 |
L |
|
2.0×10−4 |
3500 |
Sander et al. 2006 |
L |
|
2.1×10−4 |
3000 |
Wilhelm et al. 1977 |
L |
|
2.2×10−4 |
2100 |
De Bruyn et al. 1995b |
M |
|
1.5×10−4 |
3800 |
Johnson and Harrison 1986 |
M |
127)
|
1.5×10−4 |
3500 |
Hoyt 1982 |
M |
127)
|
2.4×10−4 |
|
Stock and Kuß 1917 |
M |
|
2.1×10−4 |
3300 |
Winkler 1906 |
M |
|
3.4×10−4 |
|
Hempel 1901 |
M |
236)
|
1.6×10−5 |
|
HSDB 2015 |
V |
|
2.0×10−4 |
3500 |
Winkler 1907 |
X |
291)
|
2.1×10−4 |
3300 |
Winkler 1907 |
X |
292)
|
|
2900 |
Kühne et al. 2005 |
Q |
|
|
3300 |
Kühne et al. 2005 |
? |
|
2.0×10−4 |
|
Yaws 1999 |
? |
|
1.9×10−4 |
|
Yaws and Yang 1992 |
? |
92)
|
References
-
De Bruyn, W. J., Swartz, E., Hu, J. H., Shorter, J. A., Davidovits, P., Worsnop, D. R., Zahniser, M. S., and Kolb, C. E.: Henry's law solubilities and Śetchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements, J. Geophys. Res., 100D, 7245-7251, doi:10.1029/95JD00217, 1995b.
-
Hempel, W.: Ueber Kohlenoxysulfid, Z. Angew. Chem., 14, 865-868, doi:10.1002/ANGE.19010143502, 1901.
-
Hoyt, S. D.: The ocean-air exchange of carbonyl sulfide (OCS) and halocarbons, Ph.D. thesis, Oregon Graduate Center, http://digitalcommons.ohsu.edu/etd/67/, 1982.
-
HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
-
Johnson, J. E. and Harrison, H.: Carbonyl sulfide concentrations in the surface waters and above the Pacific Ocean, J. Geophys. Res., 91D, 7883-7888, doi:10.1029/JD091ID07P07883, 1986.
-
Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
-
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
-
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
-
Stock, A. and Kuß, E.: Zur Kenntnis des Kohlenoxysulfides COS, Ber. Dtsch. Chem. Ges., 50, 159-164, doi:10.1002/CBER.19170500125, 1917.
-
Warneck, P. and Williams, J.: The Atmospheric Chemist's Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0, 2012.
-
Wilhelm, E., Battino, R., and Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219-262, doi:10.1021/CR60306A003, 1977.
-
Winkler, L. W.: Gesetzmässigkeit bei der Absorption der Gase in Flüssigkeiten, Z. Phys. Chem., 55, 344-354, doi:10.1515/ZPCH-1906-5518, 1906.
-
Winkler, L. W.: Math. Termesz. Ertesitö, 25, 86, 1907.
-
Yaws, C. L., ed.: Chemical Properties Handbook, McGraw-Hill, Inc., 1999.
-
Yaws, C. L. and Yang, H.-C.: Henry's law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181-206, Gulf Publishing Company, Houston, TX, 1992.
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
92) |
Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species. |
127) |
Solubility in sea water. |
236) |
Value at T = 287 K. |
291) |
Value given here as quoted by Booth and Jolley (1943). |
292) |
Value given here as quoted by Loomis (1928). |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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