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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsHydrocarbons (C, H)Polynuclear aromatics → dibenz[a,h]anthracene

FORMULA:C22H14
CAS RN:53-70-3
STRUCTURE
(FROM NIST):
InChIKey:LHRCREOYAASXPZ-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.8×102 12000 Abou-Naccoul et al. 2014 V
5.8×103 Mackay et al. 2006a V
1.3×102 Eastcott et al. 1988 V
1.2 7800 Paasivirta et al. 1999 T
1.4×102 Smith et al. 1993 C
1.4×102 HSDB 2015 Q 38)
1.2×101 Hilal et al. 2008 Q
8.3×101 Ferreira 2001 Q 9)

References

  • Abou-Naccoul, R., Mokbel, I., Bassil, G., Saab, J., Stephan, K., and Jose, J.: Aqueous solubility (in the range between 298.15 and 338.15 K), vapor pressures (in the range between 10−5 and 80 Pa) and Henry's law constant of 1,2,3,4-dibenzanthracene and 1,2,5,6-dibenzanthracene, Chemosphere, 95, 41-49, doi:10.1016/J.CHEMOSPHERE.2013.08.010, 2014.
  • Eastcott, L., Shiu, W. Y., and Mackay, D.: Environmentally relevant physical-chemical properties of hydrocarbons: A review of data and development of simple correlations, Oil Chem. Pollut., 4, 191-216, doi:10.1016/S0269-8579(88)80020-0, 1988.
  • Ferreira, M. M. C.: Polycyclic aromatic hydrocarbons: a QSPR study, Chemosphere, 44, 125-146, doi:10.1016/S0045-6535(00)00275-7, 2001.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. I of Introduction and Hydrocarbons , CRC/Taylor & Francis Group, 2006a.
  • Paasivirta, J., Sinkkonen, S., Mikkelson, P., Rantio, T., and Wania, F.: Estimation of vapor pressures, solubilities and Henry's law constants of selected persistent organic pollutants as functions of temperature, Chemosphere, 39, 811-832, doi:10.1016/S0045-6535(99)00016-8, 1999.
  • Smith, J. R., Neuhauser, E. F., Middleton, A. C., Cunningham, J. J., Weightman, R. L., and Linz, D. G.: Treatment of organically contaminated groundwaters in municipal activated sludge systems, Water Environ. Res., 65, 804-818, doi:10.2175/WER.65.7.2, 1993.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
38) Calculated based on the method by Meylan and Howard (1991).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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