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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Aldehydes (RCHO) → 3-methylbutanal

FORMULA:C5H10O
TRIVIAL NAME: isovaleraldehyde
CAS RN:590-86-3
STRUCTURE
(FROM NIST):
InChIKey:YGHRJJRRZDOVPD-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.1×10−2 Kim and Kim 2014 M
2.6×10−2 Pollien et al. 2003 M
2.0×10−2 Nelson and Hoff 1968 M 115)
2.5×10−2 HSDB 2015 V
7.3×10−2 Hilal et al. 2008 Q
9.8×10−3 Hertel et al. 2007 Q 194)

References

  • Hertel, M. O., Scheuren, H., Sommer, K., and Glas, K.: Limiting separation factors and limiting activity coefficients for hexanal, 2-methylbutanal, 3-methylbutanal, and dimethylsulfide in water at (98.1 to 99.0) ° C, J. Chem. Eng. Data, 52, 148-150, doi:10.1021/JE060324O, 2007.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Kim, Y.-H. and Kim, K.-H.: Recent advances in thermal desorption-gas chromatography-mass spectrometery method to eliminate the matrix effect between air and water samples: Application to the accurate determination of Henry's law constant, J. Chromatogr. A, 1342, 78-85, doi:10.1016/J.CHROMA.2014.03.040, 2014.
  • Nelson, P. E. and Hoff, J. E.: Food volatiles: Gas chromatographic determination of partition coefficients in water-lipid systems, Int. J. Mass Spectrom., 228, 479-482, doi:10.1111/J.1365-2621.1968.TB03659.X, 1968.
  • Pollien, P., Jordan, A., Lindinger, W., and Yeretzian, C.: Liquid-air partitioning of volatile compounds in coffee: dynamic measurements using proton-transfer-reaction mass spectrometry, Int. J. Mass Spectrom., 228, 69-80, doi:10.1016/S1387-3806(03)00197-0, 2003.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

115) Value at T = 301 K.
194) Value at T = 372 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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