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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with sulfur (S)Sulfur (C, H, O, N, Cl, S) → dimethyl disulfide

FORMULA:CH3SSCH3
CAS RN:624-92-0
STRUCTURE
(FROM NIST):
InChIKey:WQOXQRCZOLPYPM-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.8×10−3 Schuhfried et al. 2011 M
6.5×10−3 3200 Falabella 2007 M 89) 130)
5.9×10−3 Pollien et al. 2003 M
9.4×10−3 4300 Przyjazny et al. 1983 M
8.3×10−3 Vitenberg et al. 1975 M 9)
1.7×10−2 Mackay et al. 2006d V
1.7×10−2 Mackay et al. 1995 V
9.0×10−3 Vitenberg et al. 1975 R 9)
3.0×10−2 Hilal et al. 2008 Q
1700 Kühne et al. 2005 Q
4.6×10−3 Nirmalakhandan et al. 1997 Q
1600 Kühne et al. 2005 ?
9.0×10−3 Abraham et al. 1990 ?

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., and Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291-300, doi:10.1039/P29900000291, 1990.
  • Falabella, J. B.: Air-water partitioning of volatile organic compounds and greenhouse gases in the presence of salts, Ph.D. thesis, Georgia Institute of Technology, https://smartech.gatech.edu/handle/1853/16221, 2007.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Mackay, D., Shiu, W. Y., and Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Oxygen, Nitrogen, and Sulfur Containing Compounds , Lewis Publishers, Boca Raton, 1995.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Nirmalakhandan, N., Brennan, R. A., and Speece, R. E.: Predicting Henry's law constant and the effect of temperature on Henry's law constant, Wat. Res., 31, 1471-1481, doi:10.1016/S0043-1354(96)00395-8, 1997.
  • Pollien, P., Jordan, A., Lindinger, W., and Yeretzian, C.: Liquid-air partitioning of volatile compounds in coffee: dynamic measurements using proton-transfer-reaction mass spectrometry, Int. J. Mass Spectrom., 228, 69-80, doi:10.1016/S1387-3806(03)00197-0, 2003.
  • Przyjazny, A., Janicki, W., Chrzanowski, W., and Staszewski, R.: Headspace gas chromatographic determination of distribution coefficients of selected organosulphur compounds and their dependence on some parameters, J. Chromatogr., 280, 249-260, doi:10.1016/S0021-9673(00)91567-X, 1983.
  • Schuhfried, E., Biasioli, F., Aprea, E., Cappellin, L., Soukoulis, C., Ferrigno, A., Märk, T. D., and Gasperi, F.: PTR-MS measurements and analysis of models for the calculation of Henry's law constants of monosulfides and disulfides, Chemosphere, 83, 311-317, doi:10.1016/J.CHEMOSPHERE.2010.12.051, 2011.
  • Vitenberg, A. G., Ioffe, B. V., Dimitrova, Z. S., and Butaeva, I. L.: Determination of gas-liquid partition coefficients by means of gas chromatographic analysis, J. Chromatogr., 112, 319-327, doi:10.1016/S0021-9673(00)99964-3, 1975.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
89) Measured at high temperature and extrapolated to T = 298.15 K.
130) Values for salt solutions are also available from this reference.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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