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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with nitrogen (N)Amines, amides, amino acids (C, H, O, N) → carbaryl

FORMULA:C12H11NO2
CAS RN:63-25-2
STRUCTURE
(FROM NIST):
InChIKey:CVXBEEMKQHEXEN-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
> 9.9×101 Mabury and Crosby 1996 M
3.6×103 Watanabe 1993 M
2.2×104 Mackay et al. 2006d V
2.3×103 Meylan and Howard 1991 V
7.7×102 Suntio et al. 1988 V 9)
2.3×103 Howard and Meylan 1997 X 181)
3.5×103 Armbrust 2000 C
1.4×103 Hilal et al. 2008 Q
3.1×103 Meylan and Howard 1991 Q

References

  • Armbrust, K. L.: Pesticide hydroxyl radical rate constants: Measurements and estimates of their importance in aquatic environments, Environ. Toxicol. Chem., 19, 2175-2180, doi:10.1897/1551-5028(2000)019<2175:PHRRCM>2.3.CO;2, 2000.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Howard, P. H. and Meylan, W. M.: Handbook of physical properties of organic chemicals, CRC Press, Lewis Publisher, Boca Raton, FL, 1997.
  • Mabury, S. A. and Crosby, D. G.: Pesticide reactivity toward hydroxyl and its relationship to field persistence, J. Agric. Food Chem., 44, 1920-1924, doi:10.1021/JF950423Y, 1996.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Meylan, W. M. and Howard, P. H.: Bond contribution method for estimating Henry's law constants, Environ. Toxicol. Chem., 10, 1283-1293, doi:10.1002/ETC.5620101007, 1991.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.
  • Watanabe, T.: Relationship between volatilization rates and physicochemical properties of some pesticides, J. Pestic. Sci., 18, 201-209, doi:10.1584/JPESTICS.18.3_201, 1993.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
181) Value given here as quoted by Hilal et al. (2008).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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