MPG

Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsHydrocarbons (C, H)Mononuclear aromatics → benzene

FORMULA:C6H6
CAS RN:71-43-2
STRUCTURE
(FROM NIST):
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.7×10−3 4200 Staudinger and Roberts 2001 L
1.6×10−3 4100 Staudinger and Roberts 1996 L
1.8×10−3 Mackay and Shiu 1981 L
1.7×10−3 Kim and Kim 2014 M
1.8×10−3 3800 Hiatt 2013 M
3.5×10−3 Zhang et al. 2013 M
1.4×10−3 2400 Lau et al. 2010 M 89)
1.7×10−3 4200 Sieg et al. 2009 M 121)
1.8×10−3 Li et al. 2008 M
2.5×10−3 Lodge and Danso 2007 M
1.4×10−3 2200 Lei et al. 2004 M 122)
Cheng et al. 2003 M 123)
1.8×10−3 Karl et al. 2003 M 31)
1.8×10−3 4200 Bakierowska and Trzeszczyński 2003 M
1.8×10−3 3700 Görgényi et al. 2002 M
1.9×10−3 3200 Bierwagen and Keller 2001 M
2.1×10−3 Kochetkov et al. 2001 M 115) 124)
1.7×10−3 Kochetkov et al. 2001 M 115) 125)
1.8×10−3 Miller and Stuart 2000 M 126)
3.7×10−3 Altschuh et al. 1999 M
1.7×10−3 Ryu and Park 1999 M
1.8×10−3 Dohnal and Hovorka 1999 M
1.8×10−3 Allen et al. 1998 M
2.2×10−3 Peng and Wan 1998 M
1.4×10−3 3300 Peng and Wan 1998 M 127)
2.2×10−3 de Wolf and Lieder 1998 M 31)
1.9×10−3 3200 Peng and Wan 1997 M
1.8×10−3 2700 Kondoh and Nakajima 1997 M
1.4×10−3 3300 Park et al. 1997 M
1.8×10−3 4200 Alaee et al. 1996 M
1.6×10−3 4300 Turner et al. 1996 M
2.1×10−3 3900 Dewulf et al. 1995 M
2.0×10−3 Nielsen et al. 1994 M
1.7×10−3 4000 Khalfaoui and Newsham 1994b M
1.9×10−3 3800 Robbins et al. 1993 M
1.7×10−3 Hoff et al. 1993 M
1.8×10−3 2300 Ettre et al. 1993 M 89)
1.5×10−3 Hansen et al. 1993 M 128)
1.7×10−3 4000 Perlinger et al. 1993 M
1.7×10−3 Li and Carr 1993 M
1.8×10−3 Li et al. 1993 M
1.5×10−3 Zhang and Pawliszyn 1993 M
1.7×10−3 4000 Cooling et al. 1992 M
1.8×10−3 Anderson 1992 M 126)
1.6×10−3 4300 Bissonette et al. 1990 M
2.0×10−3 Guitart et al. 1989 M 19)
1.8×10−3 3200 Ashworth et al. 1988 M 103)
1.7×10−3 Keeley et al. 1988 M
2.0×10−3 Hellmann 1987 M 31)
1.3×10−3 Yurteri et al. 1987 M 9)
1.8×10−3 3600 Tsonopoulos and Wilson 1983 M
1.7×10−3 3900 Sanemasa et al. 1982 M
1.8×10−3 4000 Leighton and Calo 1981 M
1.7×10−3 3500 Sanemasa et al. 1981 M
1.2×10−3 5300 Ervin et al. 1980 M
1.8×10−3 Warner et al. 1980 M
1.8×10−3 Mackay et al. 1979 M
1.1×10−3 Sato and Nakajima 1979a M 19)
1.6×10−3 3800 Tsibul'skii et al. 1979 M
1.8×10−3 4200 Green and Frank 1979 M
1.8×10−3 Vitenberg et al. 1975 M
1.2×10−3 Vitenberg et al. 1974 M 9)
1.7×10−3 4400 Brown and Wasik 1974 M
2.1×10−3 4500 Hartkopf and Karger 1973 M
1.6×10−3 4500 Wasik and Tsang 1970 M
1.5×10−3 Saylor et al. 1938 M 23)
3.5×10−4 Abraham and Acree 2007 V
1.8×10−3 Mackay et al. 2006a V
1.8×10−3 Kochetkov et al. 2001 V
1.8×10−3 Shiu and Ma 2000 V
1.8×10−3 Shiu and Mackay 1997 V
1.8×10−3 Park et al. 1997 V
1.8×10−3 Mackay et al. 1992a V
1.8×10−3 Hwang et al. 1992 V
1.8×10−3 Eastcott et al. 1988 V
1.8×10−3 3800 Abraham 1984 V
1.8×10−3 3600 Ben-Naim and Wilf 1980 V
1.8×10−3 Warner et al. 1980 V
1.8×10−3 Hine and Mookerjee 1975 V
1.8×10−3 4100 Mackay and Leinonen 1975 V
1.8×10−3 3800 Andon et al. 1954 V 129)
1.8×10−3 Bohon and Claussen 1951 V
1.8×10−3 Mackay et al. 1979 T
3800 Gill et al. 1976 T 100)
1.8×10−3 2200 Goldstein 1982 X 116)
1.8×10−3 Sieg et al. 2008 C
1.8×10−3 Schüürmann 2000 C 7)
1.8×10−3 Smith et al. 1993 C 9)
1.8×10−3 Ryan et al. 1988 C
1.8×10−3 Shen 1982 C
1.7×10−3 Hilal et al. 2008 Q
4000 Kühne et al. 2005 Q
2.2×10−3 Nirmalakhandan and Speece 1988a Q
1.8×10−3 Arbuckle 1983 Q
3700 Kühne et al. 2005 ?
1.8×10−3 Yaws and Yang 1992 ? 92)
1.8×10−3 Abraham et al. 1990 ?
2.2×10−3 Mackay and Yeun 1983 ?

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  • Vitenberg, A. G., Ioffe, B. V., Dimitrova, Z. S., and Butaeva, I. L.: Determination of gas-liquid partition coefficients by means of gas chromatographic analysis, J. Chromatogr., 112, 319-327, doi:10.1016/S0021-9673(00)99964-3, 1975.
  • Warner, H. P., Cohen, J. M., and Ireland, J. C.: Determination of Henry's law constants of selected priority pollutants, Tech. rep., U.S. EPA, Municipal Environmental Research Laboratory, Wastewater Research Division, Cincinnati, Ohio, 45268, USA, 1980.
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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

7) Several references are given in the list of Henry's law constants but not assigned to specific species.
9) Value at T = 293 K.
19) Value at T = 310 K.
23) Value at T = 303 K.
31) Value at T = 295 K.
89) Measured at high temperature and extrapolated to T = 298.15 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
100) Calculated from the solvation enthalpy, using the van 't Hoff equation.
103) The value is most probably taken from the report by Howe et al. (1987).
115) Value at T = 301 K.
116) Value given here as quoted by Staudinger and Roberts (1996).
121) Sieg et al. (2009) also provide data for supercooled water. Here, only data above 0 °C were used to calculate the temperature dependence.
122) Extrapolated from data above 298 K.
123) It was found that H changes with the concentration of the solution.
124) Value obtained by applying a modified batch air-stripping method, otherwise called the vapor entry loop (VEL) method, see Kochetkov et al. (2001) for details.
125) Value obtained by applying the static head space (HS) method, see Kochetkov et al. (2001) for details.
126) Value at T = 296 K.
127) Solubility in sea water.
128) Value at T = 302 K.
129) Calculated using Gh and Hh from Table 2 in Andon et al. (1954). Note that the thermodynamic functions in that table are not based on their α in Table 1. Instead, the expression exp(−Gh/(RT)) yields the Henry's law constant Hxp in the unit 1/atm.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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