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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorocarbons (C, H, Cl) → dichloromethane

FORMULA:CH2Cl2
TRIVIAL NAME: methylene chloride
CAS RN:75-09-2
STRUCTURE
(FROM NIST):
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
3.6×10−3 4100 Sander et al. 2011 L
3.9×10−3 3700 Warneck 2007 L
3.6×10−3 4100 Sander et al. 2006 L
3.6×10−3 4100 Staudinger and Roberts 2001 L
3.6×10−3 4100 Staudinger and Roberts 1996 L
3.8×10−3 Mackay and Shiu 1981 L
4.0×10−3 3900 Hiatt 2013 M
3.5×10−3 2300 Chen et al. 2012 M
3.2×10−3 Helburn et al. 2008 M
3.3×10−3 4200 Moore 2000 M 127)
3.9×10−3 David et al. 2000 M 126)
4.1×10−3 Ryu and Park 1999 M
3.4×10−3 Chiang et al. 1998 M 9) 250)
5.1×10−3 Hovorka and Dohnal 1997 M 9)
3.7×10−3 3200 Kondoh and Nakajima 1997 M
4.3×10−3 3500 Park et al. 1997 M
4.1×10−3 Hoff et al. 1993 M
3.8×10−3 Li et al. 1993 M
3.9×10−3 3800 Wright et al. 1992 M
3.9×10−3 3500 Tse et al. 1992 M
3.4×10−3 Guitart et al. 1989 M 19)
3.4×10−3 4300 Ashworth et al. 1988 M 103)
4.6×10−3 3800 Gossett 1987 M
5.7×10−3 Hellmann 1987 M 31)
5.2×10−3 Yurteri et al. 1987 M 9)
3.8×10−3 4500 Gossett et al. 1985 M
3.4×10−3 4200 Lincoff and Gossett 1984 M
3.0×10−3 3600 Leighton and Calo 1981 M
3.1×10−3 Warner et al. 1980 M
2.8×10−3 Sato and Nakajima 1979b M 19)
3.3×10−3 Pearson and McConnell 1975 M 9) 248)
4.2×10−3 4400 Hartkopf and Karger 1973 M
4.1×10−3 4000 Rex 1906 M
2.7×10−3 Mackay et al. 2006b V
3.5×10−3 4100 Fogg and Sangster 2003 V
4.0×10−3 Park et al. 1997 V
5.9×10−3 Mackay et al. 1993 V
2.9×10−3 Hwang et al. 1992 V
3.2×10−3 Warner et al. 1980 V
4.0×10−3 Dilling 1977 V 249)
1.2×10−2 Dilling 1977 V 66)
4.3×10−3 Hine and Mookerjee 1975 V
4.0×10−3 Dilling et al. 1975 V
3.1×10−3 3600 Goldstein 1982 X 116)
4.2×10−3 Harrison et al. 1993 C
3.4×10−3 Harrison et al. 1993 C
4.7×10−3 Ryan et al. 1988 C
3.1×10−3 Shen 1982 C
3.7×10−3 Dilling 1977 C
3.7×10−3 Dilling et al. 1975 C
9.0×10−3 Hilal et al. 2008 Q
3000 Kühne et al. 2005 Q
2.2×10−3 Nirmalakhandan and Speece 1988a Q
3.3×10−3 Mackay et al. 2006b ?
3900 Kühne et al. 2005 ?
4.0×10−3 Yaws 1999 ?
3.3×10−3 Mackay et al. 1993 ?
4.0×10−3 Yaws and Yang 1992 ? 92)
3.7×10−3 Abraham et al. 1990 ?

References

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  • Gossett, J. M., Cameron, C. E., Eckstrom, B. P., Goodman, C., and Lincoff, A. H.: Mass transfer coefficients and Henry's constants for packed-tower air stripping of volatile organics: Measurements and Correlations, Final Report ESL-TR-85-18, Engineering and Services Laboratory, Tyndall Air Force Base, FL, 1985.
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  • Hartkopf, A. and Karger, B. L.: Study of the interfacial properties of water by gas chromatography, Acc. Chem. Res., 6, 209-216, doi:10.1021/AR50066A006, 1973.
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  • Hellmann, H.: Model tests on volatilization of organic trace substances in surfaces waters, Fresenius J. Anal. Chem., 328, 475-479, doi:10.1007/BF00475967, 1987.
  • Hiatt, M. H.: Determination of Henry's law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902-908, doi:10.1021/JE3010535, 2013.
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  • Hine, J. and Mookerjee, P. K.: The intrinsic hydrophilic character of organic compounds. Correlations in terms of structural contributions, J. Org. Chem., 40, 292-298, doi:10.1021/JO00891A006, 1975.
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  • Hovorka, S. and Dohnal, V.: Determination of air-water partitioning of volatile halogenated hydrocarbons by the inert gas stripping method, J. Chem. Eng. Data, 42, 924-933, doi:10.1021/JE970046G, 1997.
  • Hwang, Y.-L., Olson, J. D., and Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759-1768, doi:10.1021/IE00007A022, 1992.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Kondoh, H. and Nakajima, T.: Optimization of headspace cryofocus gas chromatography/mass spectrometry for the analysis of 54 volatile organic compounds, and the measurement of their Henry's constants, J. Environ. Chem., 7, 81-89, doi:10.5985/JEC.7.81, 1997.
  • Leighton, D. T. and Calo, J. M.: Distribution coefficients of chlorinated hydrocarbons in dilute air-water systems for groundwater contamination applications, J. Chem. Eng. Data, 26, 382-385, doi:10.1021/JE00026A010, 1981.
  • Li, J., Dallas, A. J., Eikens, D. I., Carr, P. W., Bergmann, D. L., Hait, M. J., and Eckert, C. A.: Measurement of large infinite dilution activity coefficients of nonelectrolytes in water by inert gas stripping and gas chromatography, Anal. Chem., 65, 3212-3218, doi:10.1021/AC00070A008, 1993.
  • Lincoff, A. H. and Gossett, J. M.: The determination of Henry's law constant for volatile organics by equilibrium partitioning in closed systems, in: Gas transfer at water surfaces, edited by Brutsaert, W. and Jirka, G. H., pp. 17-25, D. Reidel Publishing Company, Dordrecht-Holland, doi:10.1007/978-94-017-1660-4_2, 1984.
  • Mackay, D. and Shiu, W. Y.: A critical review of Henry's law constants for chemicals of environmental interest, J. Phys. Chem. Ref. Data, 10, 1175-1199, doi:10.1063/1.555654, 1981.
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  • Nirmalakhandan, N. N. and Speece, R. E.: QSAR model for predicting Henry's constant, Environ. Sci. Technol., 22, 1349-1357, doi:10.1021/ES00176A016, 1988a.
  • Park, S.-J., Han, S.-D., and Ryu, S.-A.: Measurement of air/water partition coefficient (Henry's law constant) by using EPICS method and their relationship with vapor pressure and water solubility, J. Korean Inst. Chem. Eng., 35, 915-920, 1997.
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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
19) Value at T = 310 K.
31) Value at T = 295 K.
66) Value at T = 275 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
103) The value is most probably taken from the report by Howe et al. (1987).
116) Value given here as quoted by Staudinger and Roberts (1996).
126) Value at T = 296 K.
127) Solubility in sea water.
248) The same data were also published in McConnell et al. (1975).
249) Values at different temperatures are from different sources. Thus a temperature dependence was not calculated.
250) Chiang et al. (1998) show vinyl chloride in their Table 2 but most probably they meant to refer to dichloromethane instead.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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