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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with sulfur (S)Sulfur (C, H, O, N, Cl, S) → carbon disulfide

FORMULA:CS2
CAS RN:75-15-0
STRUCTURE
(FROM NIST):
InChIKey:QGJOPFRUJISHPQ-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
6.1×10−4 3900 Warneck and Williams 2012 L
6.1×10−4 4300 Sander et al. 2011 L
6.1×10−4 4300 Sander et al. 2006 L
5.7×10−4 3800 Hiatt 2013 M
5.4×10−4 2800 De Bruyn et al. 1995b M
6.2×10−4 3800 Elliott 1989 M
5.4×10−4 4300 Rex 1906 M
5.7×10−4 Mackay et al. 2006d V
5.7×10−4 Mackay et al. 1995 V
8.0×10−4 Hwang et al. 1992 V
4.5×10−4 4100 Winkler 1906 V
7.5×10−4 1200 Goldstein 1982 X 116)
9.4×10−5 Yaws 1999 ?
5.1×10−4 Yaws and Yang 1992 ? 92)
Kruis and May 1962 ? 287)
Booth and Jolley 1943 ? 288)
Booth and Jolley 1943 ? 289)

References

  • Booth, N. and Jolley, L. J.: The removal of organic sulphur compounds from gases, J. Soc. Chem. Ind., 62, 87-88, doi:10.1002/JCTB.5000620603, 1943.
  • De Bruyn, W. J., Swartz, E., Hu, J. H., Shorter, J. A., Davidovits, P., Worsnop, D. R., Zahniser, M. S., and Kolb, C. E.: Henry's law solubilities and Śetchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements, J. Geophys. Res., 100D, 7245-7251, doi:10.1029/95JD00217, 1995b.
  • Elliott, S.: The solubility of carbon disulfide vapor in natural aqueous systems, Atmos. Environ., 23, 1977-1980, doi:10.1016/0004-6981(89)90523-4, 1989.
  • Goldstein, D. J.: Air and steam stripping of toxic pollutants, Appendix 3: Henry's law constants, Tech. Rep. EPA-68-03-002, Industrial Environmental Research Laboratory, Cincinnati, OH, USA, 1982.
  • Hiatt, M. H.: Determination of Henry's law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902-908, doi:10.1021/JE3010535, 2013.
  • Hwang, Y.-L., Olson, J. D., and Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759-1768, doi:10.1021/IE00007A022, 1992.
  • Kruis, A. and May, A.: Lösungsgleichgewichte von Gasen mit Flüssigkeiten, in: Landolt-Börnstein II/2b, edited by Schäfer, K. and Lax, E., pp. (1-1)-(1-210), Springer Verlag, Berlin, 1962.
  • Mackay, D., Shiu, W. Y., and Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Oxygen, Nitrogen, and Sulfur Containing Compounds , Lewis Publishers, Boca Raton, 1995.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Rex, A.: Über die Löslichkeit der Halogenderivate der Kohlenwasserstoffe in Wasser, Z. Phys. Chem., 55, 355-370, doi:10.1515/ZPCH-1906-5519, 1906.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Warneck, P. and Williams, J.: The Atmospheric Chemist's Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0, 2012.
  • Winkler, L. W.: Gesetzmässigkeit bei der Absorption der Gase in Flüssigkeiten, Z. Phys. Chem., 55, 344-354, doi:10.1515/ZPCH-1906-5518, 1906.
  • Yaws, C. L., ed.: Chemical Properties Handbook, McGraw-Hill, Inc., 1999.
  • Yaws, C. L. and Yang, H.-C.: Henry's law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181-206, Gulf Publishing Company, Houston, TX, 1992.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
116) Value given here as quoted by Staudinger and Roberts (1996).
287) Kruis and May (1962) present data based on Booth and Jolley (1943). However, these data appear to be incorrect.
288) Booth and Jolley (1943) converted data from Rex (1906) to another unit. However, this was apparently not done correctly.
289) Booth and Jolley (1943) present data from Chancel and Parmentier (1885). However, in that paper only the solubility at an unknown partial pressure of CS2 was measured.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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