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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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References

Errata

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with fluorine (F)Organic fluorine → tetrafluoromethane

FORMULA:CF4
TRIVIAL NAME: carbontetrafluoride
CAS RN:75-73-0
STRUCTURE
(FROM NIST):
InChIKey:TXEYQDLBPFQVAA-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.1×10−6 2300 Warneck and Williams 2012 L
2.1×10−6 1800 Sander et al. 2011 L
2.1×10−6 1800 Wilhelm et al. 1977 L
2.0×10−6 2000 Reichl 1995 M
2.2×10−6 1400 Scharlin and Battino 1994 M
2.1×10−6 Park et al. 1982 M
2.0×10−6 2300 Wen and Muccitelli 1979 M
2.2×10−6 1900 Ashton et al. 1968 M
2.0×10−6 1500 Morrison and Johnstone 1954 M
1.9×10−6 Hine and Mookerjee 1975 V
1.9×10−6 Irmann 1965 C
9.2×10−6 Hilal et al. 2008 Q
2200 Kühne et al. 2005 Q
1.0×10−6 -840 Bonifácio et al. 2001 Q
5.4×10−6 Nirmalakhandan and Speece 1988a Q
1.6×10−6 Irmann 1965 Q
1900 Kühne et al. 2005 ?
1.9×10−6 Yaws 1999 ?
1.8×10−6 Yaws and Yang 1992 ? 92)

References

  • Ashton, J. T., Dawe, R. A., Miller, K. W., Smith, E. B., and Stickings, B. J.: The solubility of certain gaseous fluorine compounds in water, J. Chem. Soc. A, pp. 1793-1796, doi:10.1039/J19680001793, 1968.
  • Bonifácio, R. P., Pádua, A. A. H., and Costa Gomes, M. F.: Perfluoroalkanes in water: experimental Henry's law coefficients for hexafluoroethane and computer simulations for tetrafluoromethane and hexafluoroethane, J. Phys. Chem. B, 105, 8403-8409, doi:10.1021/JP010597K, 2001.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Hine, J. and Mookerjee, P. K.: The intrinsic hydrophilic character of organic compounds. Correlations in terms of structural contributions, J. Org. Chem., 40, 292-298, doi:10.1021/JO00891A006, 1975.
  • Irmann, F.: Eine einfache Korrelation zwischen Wasserlöslichkeit und Struktur von Kohlenwasserstoffen und Halogenkohlenwasserstoffen, Chem.-Ing.-Tech., 37, 789-798, doi:10.1002/CITE.330370802, 1965.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Morrison, T. J. and Johnstone, N. B.: Solubilities of the inert gases in water, J. Chem. Soc., pp. 3441-3446, doi:10.1039/JR9540003441, 1954.
  • Nirmalakhandan, N. N. and Speece, R. E.: QSAR model for predicting Henry's constant, Environ. Sci. Technol., 22, 1349-1357, doi:10.1021/ES00176A016, 1988a.
  • Park, T., Rettich, T. R., Battino, R., Peterson, D., and Wilhelm, E.: Solubility of gases in liquids. 14. Bunsen coefficients for several fluorine-containing gases (Freons) dissolved in water at 298.15 K, J. Chem. Eng. Data, 27, 324-326, doi:10.1021/JE00029A027, 1982.
  • Reichl, A.: Messung und Korrelierung von Gaslöslichkeiten halogenierter Kohlenwasserstoffe, Ph.D. thesis, Technische Universität Berlin, Germany, 1995.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Scharlin, P. and Battino, R.: Solubility of CCl2F2, CClF3, CF4 and c-C4F8 in H2O and D2O at 288 to 318 K and 101.325 kPa. Thermodynamics of transfer of gases from H2O to D2O, Fluid Phase Equilib., 95, 137-147, doi:10.1016/0378-3812(94)80066-9, 1994.
  • Warneck, P. and Williams, J.: The Atmospheric Chemist's Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0, 2012.
  • Wen, W.-Y. and Muccitelli, J. A.: Thermodynamics of some perfluorocarbon gases in water, J. Solution Chem., 8, 225-246, doi:10.1007/BF00648882, 1979.
  • Wilhelm, E., Battino, R., and Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219-262, doi:10.1021/CR60306A003, 1977.
  • Yaws, C. L., ed.: Chemical Properties Handbook, McGraw-Hill, Inc., 1999.
  • Yaws, C. L. and Yang, H.-C.: Henry's law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181-206, Gulf Publishing Company, Houston, TX, 1992.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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