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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with sulfur (S)Sulfur (C, H, O, N, Cl, S) → S-ethyl dipropylthiocarbamate

FORMULA:C9H19NOS
TRIVIAL NAME: eptam; EPTC
CAS RN:759-94-4
STRUCTURE
(FROM NIST):
InChIKey:GUVLYNGULCJVDO-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.6×10−1 9100 Reyes-Pérez et al. 2008 M
3.8×10−2 4800 Breiter et al. 1998 M
6.2×10−1 HSDB 2015 V
9.8×10−1 Mackay et al. 2006d V
4.2×10−1 Breiter et al. 1998 V
9.8×10−1 Suntio et al. 1988 V 9)
7.4×10−1 Burkhard and Guth 1981 V
8.2×10−1 Hilal et al. 2008 Q
4800 Kühne et al. 2005 Q
4800 Kühne et al. 2005 ?

References

  • Breiter, W. A., Baker, J. M., and Koskinen, W. C.: Direct measurement of Henry's constant for S-ethyl N,N-di-n-propylthiocarbamate, J. Agric. Food Chem., 46, 1624-1629, doi:10.1021/JF980042V, 1998.
  • Burkhard, N. and Guth, J. A.: Rate of volatilisation of pesticides from soil surfaces; comparison of calculated results with those determined in a laboratory model system, Pestic. Sci., 12, 37-44, doi:10.1002/PS.2780120106, 1981.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides , CRC/Taylor & Francis Group, 2006d.
  • Reyes-Pérez, E., Le Calvé, S., and Mirabel, P.: UV absorption spectrum and Henry's law constant of EPTC, Atmos. Environ., 42, 7940-7946, doi:10.1016/J.ATMOSENV.2008.07.017, 2008.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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