When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
| FORMULA: | C2F3Cl3 |
|
TRIVIAL NAME:
|
R113
|
|
CAS RN: | 76-13-1 |
STRUCTURE
(FROM
NIST):
|
|
|
InChIKey: | AJDIZQLSFPQPEY-UHFFFAOYSA-N |
| Hcp |
d ln Hcp / d (1/T) |
Reference |
Type |
Notes |
| [mol/(m3Pa)] |
[K] |
|
|
|
| 2.0×10−4 |
5700 |
Hiatt 2013 |
M |
|
| 2.9×10−5 |
4300 |
Dewulf et al. 1999 |
M |
|
| 3.1×10−5 |
4300 |
Bu and Warner 1995 |
M |
|
| 2.8×10−5 |
6500 |
Reichl 1995 |
M |
|
| 3.4×10−5 |
3200 |
Ashworth et al. 1988 |
M |
103)
|
| 1.9×10−5 |
|
HSDB 2015 |
V |
|
|
|
Mackay et al. 2006b |
V |
256)
|
| 8.8×10−6 |
|
Mackay et al. 1993 |
V |
|
| 2.0×10−5 |
|
Hine and Mookerjee 1975 |
V |
|
| 1.8×10−4 |
|
Hilal et al. 2008 |
Q |
|
|
3700 |
Kühne et al. 2005 |
Q |
|
| 3.1×10−5 |
|
Mackay et al. 2006b |
? |
|
|
3800 |
Kühne et al. 2005 |
? |
|
| 3.1×10−5 |
|
Mackay et al. 1993 |
? |
|
| 2.0×10−5 |
|
Yaws and Yang 1992 |
? |
92)
|
| 2.0×10−5 |
|
Abraham et al. 1990 |
? |
|
References
-
Abraham, M. H., Whiting, G. S., Fuchs, R., and Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291-300, doi:10.1039/P29900000291, 1990.
-
Ashworth, R. A., Howe, G. B., Mullins, M. E., and Rogers, T. N.: Air-water partitioning coefficients of organics in dilute aqueous solutions, J. Hazard. Mater., 18, 25-36, doi:10.1016/0304-3894(88)85057-X, 1988.
-
Bu, X. and Warner, M. J.: Solubility of chlorofluorocarbon 113 in water and seawater, Deep-Sea Res. I, 42, 1151-1161, doi:10.1016/0967-0637(95)00052-8, 1995.
-
Dewulf, J., van Langenhove, H., and Everaert, P.: Determination of Henry's law coefficients by combination of the equilibrium partitioning in closed systems and solid-phase microextraction techniques, J. Chromatogr. A, 830, 353-363, doi:10.1016/S0021-9673(98)00877-2, 1999.
-
Hiatt, M. H.: Determination of Henry's law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902-908, doi:10.1021/JE3010535, 2013.
-
Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
-
Hine, J. and Mookerjee, P. K.: The intrinsic hydrophilic character of organic compounds. Correlations in terms of structural contributions, J. Org. Chem., 40, 292-298, doi:10.1021/JO00891A006, 1975.
-
HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
-
Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
-
Mackay, D., Shiu, W. Y., and Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. III of Volatile Organic Chemicals , Lewis Publishers, Boca Raton, 1993.
-
Mackay, D., Shiu, W. Y., Ma, K. C., and Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. II of Halogenated Hydrocarbons , CRC/Taylor & Francis Group, 2006b.
-
Reichl, A.: Messung und Korrelierung von Gaslöslichkeiten halogenierter Kohlenwasserstoffe, Ph.D. thesis, Technische Universität Berlin, Germany, 1995.
-
Yaws, C. L. and Yang, H.-C.: Henry's law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181-206, Gulf Publishing Company, Houston, TX, 1992.
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
| 92) |
Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species. |
| 103) |
The value is most probably taken from the report by Howe et al. (1987). |
| 256) |
Mackay et al. (2006b) list a vapor pressure p, a solubility c, and a Henry's law constant calculated as p/c. However, the data are internally inconsistent and deviate by more than 10 %. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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