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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesHydrogen (H) → hydrogen peroxide

FORMULA:H2O2
CAS RN:7722-84-1
STRUCTURE
(FROM NIST):
InChIKey:MHAJPDPJQMAIIY-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
9.1×102 6600 Warneck and Williams 2012 L
8.3×102 7600 Sander et al. 2011 L
7.6×102 7300 Sander et al. 2006 L
9.8×102 6100 Fogg and Sangster 2003 L 15)
1.1×103 7000 Huang and Chen 2010 M
8.2×102 7400 O'Sullivan et al. 1996 M
9.9×102 6300 Lind and Kok 1994 M 16)
Staffelbach and Kok 1993 M 17)
8.5×102 6500 Zhou and Lee 1992 M
6.7×102 7900 Hwang and Dasgupta 1985 M
1.4×103 Yoshizumi et al. 1984 M 9)
9.6×102 6600 Chameides 1984 T
7.0×102 7000 Martin and Damschen 1981 T
6.4×101 Hilal et al. 2008 Q
7.0×102 7300 Seinfeld 1986 ? 7)
7.0×102 7300 Hoffmann and Jacob 1984 ? 7)
Pandis and Seinfeld 1989 W 18)

References

  • Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89D, 4739-4755, doi:10.1029/JD089ID03P04739, 1984.
  • Fogg, P. and Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc., 2003.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Hoffmann, M. R. and Jacob, D. J.: Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: An application to nighttime fog water chemistry, in: SO2, NO and NO2 Oxidation Mechanisms: Atmospheric Considerations, edited by Calvert, J. G., pp. 101-172, Butterworth Publishers, Boston, MA, 1984.
  • Huang, D. and Chen, Z.: Reinvestigation of the Henry's law constant for hydrogen peroxide with temperature and acidity variation, J. Environ. Sci., 22, 570-574, doi:10.1016/S1001-0742(09)60147-9, 2010.
  • Hwang, H. and Dasgupta, P. G.: Thermodynamics of the hydrogen peroxide-water system, Environ. Sci. Technol., 19, 255-258, doi:10.1021/ES00133A006, 1985.
  • Lind, J. A. and Kok, G. L.: Correction to "Henry's law determinations for aqueous solutions of hydrogen peroxide, methylhydroperoxide, and peroxyacetic acid" by John A. Lind and Gregory L. Kok, J. Geophys. Res., 99D, 21 119, 1994.
  • Martin, L. R. and Damschen, D. E.: Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH, Atmos. Environ., 15, 1615-1621, doi:10.1016/0004-6981(81)90146-3, 1981.
  • O'Sullivan, D. W., Lee, M., Noone, B. C., and Heikes, B. G.: Henry's law constant determinations for hydrogen peroxide, methyl hydroperoxide, hydroxymethyl hydroperoxide, ethyl hydroperoxide, and peroxyacetic acid, J. Phys. Chem., 100, 3241-3247, doi:10.1021/JP951168N, 1996.
  • Pandis, S. N. and Seinfeld, J. H.: Sensitivity analysis of a chemical mechanism for aqueous-phase atmospheric chemistry, J. Geophys. Res., 94D, 1105-1126, doi:10.1029/JD094ID01P01105, 1989.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY, 1986.
  • Staffelbach, T. A. and Kok, G. L.: Henry's law constants for aqueous solutions of hydrogen peroxide and hydroxymethyl hydroperoxide, J. Geophys. Res., 98D, 12 713-12 717, doi:10.1029/93JD01022, 1993.
  • Warneck, P. and Williams, J.: The Atmospheric Chemist's Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0, 2012.
  • Yoshizumi, K., Aoki, K., Nouchi, I., Okita, T., Kobayashi, T., Kamakura, S., and Tajima, M.: Measurements of the concentration in rainwater and of the Henry's law constant of hydrogen peroxide, Atmos. Environ., 18, 395-401, doi:10.1016/0004-6981(84)90114-8, 1984.
  • Zhou, X. and Lee, Y.-N.: Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide, J. Phys. Chem., 96, 265-272, doi:10.1021/J100180A051, 1992.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

7) Several references are given in the list of Henry's law constants but not assigned to specific species.
9) Value at T = 293 K.
15) Erratum for page 264 of Fogg and Sangster (2003): The second value from their Ref. [10] refers to 291.15 K, not 281.15 K.
16) This value is a correction of the solubility published by Lind and Kok (1986).
17) This value was measured at low pH. It is superseded by a later publication of the same group (Lind and Kok 1994).
18) Pandis and Seinfeld (1989) cite an incorrect value from Lind and Kok (1986), see erratum by Lind and Kok (1994).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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