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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesSulfur (S) → hydrogen sulfide

FORMULA:H2S
CAS RN:7783-06-4
STRUCTURE
(FROM NIST):
InChIKey:RWSOTUBLDIXVET-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.0×10−3 2100 Sander et al. 2011 L
1.0×10−3 2100 Sander et al. 2006 L
1.0×10−3 2000 Fernández-Prini et al. 2003 L 1)
1.0×10−3 2200 Carroll and Mather 1989 L
1.0×10−3 2000 Yoo et al. 1986 L
1.0×10−3 2100 Edwards et al. 1978 L
1.0×10−3 2100 Wilhelm et al. 1977 L
9.1×10−4 1700 Rinker and Sandall 2000 M
8.6×10−4 2100 De Bruyn et al. 1995b M
1.1×10−3 2300 Suleimenov and Krupp 1994 M
9.4×10−4 2300 Barrett et al. 1988 M
1.0×10−3 2100 Winkler 1906 M
9.6×10−4 2000 Iliuta and Larachi 2007 R
1.0×10−3 Hine and Weimar 1965 R
1.0×10−3 1900 Fogg and Young 1988 X 5)
1.0×10−3 2300 Dean 1992 ? 6)
Chapoy et al. 2005 W 74)

References

  • Barrett, T. J., Anderson, G. M., and Lugowski, J.: The solubility of hydrogen sulphide in 0-5 m NaCl solutions at 25 °-95 ° C and one atmosphere, Geochim. Cosmochim. Acta, 52, 807-811, doi:10.1016/0016-7037(88)90352-3, 1988.
  • Carroll, J. J. and Mather, A. E.: The solubility of hydrogen sulphide in water from 0 to 90 ° C and pressures to 1 MPa, Geochim. Cosmochim. Acta, 53, 1163-1170, doi:10.1016/0016-7037(89)90053-7, 1989.
  • Chapoy, A., Mohammadi, A. H., Tohidi, B., Valtz, A., and Richon, D.: Experimental measurement and phase behavior modeling of hydrogen sulfide-water binary system, Ind. Eng. Chem. Res., 44, 7567-7574, doi:10.1021/IE050201H, 2005.
  • Dean, J. A.: Lange's Handbook of Chemistry, McGraw-Hill, Inc., 1992.
  • De Bruyn, W. J., Swartz, E., Hu, J. H., Shorter, J. A., Davidovits, P., Worsnop, D. R., Zahniser, M. S., and Kolb, C. E.: Henry's law solubilities and Śetchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements, J. Geophys. Res., 100D, 7245-7251, doi:10.1029/95JD00217, 1995b.
  • Edwards, T. J., Maurer, G., Newman, J., and Prausnitz, J. M.: Vapor-liquid equilibria in multicomponent aqueous solutions of volatile weak electrolytes, AIChE J., 24, 966-976, doi:10.1002/AIC.690240605, 1978.
  • Fernández-Prini, R., Alvarez, J. L., and Harvey, A. H.: Henry's constants and vapor-liquid distribution constants for gaseous solutes in H2O and D2O at high temperatures, J. Phys. Chem. Ref. Data, 32, 903-916, doi:10.1063/1.1564818, 2003.
  • Fogg, P. G. T. and Young, C. L., eds.: IUPAC Solubility Data Series, vol. 32 of Hydrogen Sulfide, Deuterium Sulfide, and Hydrogen Selenide , Pergamon Press, Oxford, England, 1988.
  • Hine, J. and Weimar, Jr., R. D.: Carbon basicity, J. Am. Chem. Soc., 87, 3387-3396, doi:10.1021/JA01093A018, 1965.
  • Iliuta, M. C. and Larachi, F.: Solubility of total reduced sulfurs (hydrogen sulfide, methyl mercaptan, dimethyl sulfide, and dimethyl disulfide) in liquids, J. Chem. Eng. Data, 52, 2-19, doi:10.1021/JE060263U, 2007.
  • Rinker, E. B. and Sandall, O. C.: Physical solubility of hydrogen sulfide in several aqueous solvents, Can. J. Chem. Eng., 78, 232-236, doi:10.1002/CJCE.5450780130, 2000.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Suleimenov, O. M. and Krupp, R. E.: Solubility of hydrogen sulfide in pure water and in NaCl solutions, from 20 to 320 ° C and at saturation pressures, Geochim. Cosmochim. Acta, 58, 2433-2444, doi:10.1016/0016-7037(94)90022-1, 1994.
  • Wilhelm, E., Battino, R., and Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219-262, doi:10.1021/CR60306A003, 1977.
  • Winkler, L. W.: Gesetzmässigkeit bei der Absorption der Gase in Flüssigkeiten, Z. Phys. Chem., 55, 344-354, doi:10.1515/ZPCH-1906-5518, 1906.
  • Yoo, K.-P., Lee, S. Y., and Lee, W. H.: Ionization and Henry's law constants for volatile, weak electrolyte water pollutants, Korean J. Chem. Eng., 3, 67-72, doi:10.1007/BF02697525, 1986.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

1) Vapor pressure data for water from Wagner and Pruss (1993) was needed to calculate H.
5) Value given here as quoted by Lide and Frederikse (1995).
6) Only the tabulated data between T = 273 K and T = 303 K from Dean (1992) were used to derive H and its temperature dependence. Above T = 303 K, the tabulated data could not be parameterized very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by Sander et al. (1995). The quantities A and α from Dean (1992) were assumed to be identical.
74) The parameter fit for the temperature dependence is incorrect. A corrected version was later presented by Iliuta and Larachi (2007).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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