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Henry's Law Constants

Rolf Sander

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Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Hydrocarbons (C, H) → Terpenes and terpenoids → α-pinene

FORMULA:C10H16
CAS RN:80-56-8
STRUCTURE
(FROM NIST):
InChIKey:GRWFGVWFFZKLTI-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.9×10−4 1800 Leng et al. 2013 M
7.4×10−5 4400 Copolovici and Niinemets 2005 M
5.8×10−4 Karl et al. 2003 M 31)
7.0×10−5 Fichan et al. 1999 M
4.7×10−5 Falk et al. 1990 M 19)
3.4×10−5 HSDB 2015 V
7.4×10−5 Copolovici and Niinemets 2005 V
7.4×10−5 Niinemets and Reichstein 2002 V
2.8×10−5 10000 Li et al. 1998 V
3.5×10−5 Hilal et al. 2008 C
3.1×10−5 Hilal et al. 2008 Q

References

  • Copolovici, L. O. and Niinemets, U.: Temperature dependencies of Henry's law constants and octanol/water partition coefficients for key plant volatile monoterpenoids, Chemosphere, 61, 1390-1400, doi:10.1016/J.CHEMOSPHERE.2005.05.003, 2005.
  • Falk, A., Gullstrand, E., Löf, A., and Wigaeus-Hjelm, E.: Liquid/air partition coefficients of four terpenes, Br. J. Ind. Med., 47, 62-64, doi:10.1136/OEM.47.1.62, 1990.
  • Fichan, I., Larroche, C., and Gros, J. B.: Water solubility, vapor pressure, and activity coefficients of terpenes and terpenoids, J. Chem. Eng. Data, 44, 56-62, doi:10.1021/JE980070+, 1999.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 2015.
  • Karl, T., Yeretzian, C., Jordan, A., and Lindinger, W.: Dynamic measurements of partition coefficients using proton-transfer-reaction mass spectrometry (PTR-MS), Int. J. Mass Spectrom., 223-224, 383-395, doi:10.1016/S1387-3806(02)00927-2, 2003.
  • Leng, C., Kish, J. D., Kelley, J., Mach, M., Hiltner, J., Zhang, Y., and Liu, Y.: Temperature-dependent Henry's law constants of atmospheric organics of biogenic origin, J. Phys. Chem. A, 117, 10 359-10 367, doi:10.1021/JP403603Z, 2013.
  • Li, J., Perdue, E. M., Pavlostathis, S. G., and Araujo, R.: Physicochemical properties of selected monoterpenes, Environ. Int., 24, 353-358, doi:10.1016/S0160-4120(98)00013-0, 1998.
  • Niinemets, U. and Reichstein, M.: A model analysis of the effects of nonspecific monoterpenoid storage in leaf tissues on emission kinetics and composition in Mediterranean sclerophyllous Quercus species, Global Biogeochem. Cycles, 16, 1110, doi:10.1029/2002GB001927, 2002.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

19) Value at T = 310 K.
31) Value at T = 295 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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