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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with nitrogen (N)Nitrates (RONO2) → 1-butyl nitrate

FORMULA:C4H9ONO2
CAS RN:928-45-0
STRUCTURE
(FROM NIST):
InChIKey:QQHZPQUHCAKSOL-UHFFFAOYSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.0×10−2 5800 Sander et al. 2011 L
1.0×10−2 5800 Sander et al. 2006 L
8.8×10−3 6000 Staudinger and Roberts 2001 L
6.3×10−3 5200 Hauff et al. 1998 M
1.0×10−2 5800 Kames and Schurath 1992 M
1.0×10−2 6000 Luke et al. 1989 M
8.5×10−3 Hauff et al. 1998 V
1.7×10−2 Hilal et al. 2008 Q
5900 Kühne et al. 2005 Q
5800 Kühne et al. 2005 ?

References

  • Hauff, K., Fischer, R. G., and Ballschmiter, K.: Determination of C1-C5 alkyl nitrates in rain, snow, white frost, and tap water by a combined codistillation head-space gas chromatography technique. Determination of Henry's law constants by head-space GC, Chemosphere, 37, 2599-2615, doi:10.1016/S0045-6535(98)00159-3, 1998.
  • Hilal, S. H., Ayyampalayam, S. N., and Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry's law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231-9236, doi:10.1021/ES8005783, 2008.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Kames, J. and Schurath, U.: Alkyl nitrates and bifunctional nitrates of atmospheric interest: Henry's law constants and their temperature dependencies, J. Atmos. Chem., 15, 79-95, doi:10.1007/BF00053611, 1992.
  • Luke, W. T., Dickerson, R. R., and Nunnermacker, L. J.: Direct measurements of the photolysis rate coefficients and Henry's law constants of several alkyl nitrates, J. Geophys. Res., 94D, 14 905-14 921, doi:10.1029/JD094ID12P14905, 1989.
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, http://jpldataeval.jpl.nasa.gov, 2006.
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, http://jpldataeval.jpl.nasa.gov, 2011.
  • Staudinger, J. and Roberts, P. V.: A critical compilation of Henry's law constant temperature dependence relations for organic compounds in dilute aqueous solutions, Chemosphere, 44, 561-576, doi:10.1016/S0045-6535(00)00505-1, 2001.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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