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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

Notes

References

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with sulfur (S)Sulfur (C, H, O, N, Cl, S) → α-endosulfan

FORMULA:C9H6Cl6O3S
TRIVIAL NAME: endosulfan I
CAS RN:959-98-8
STRUCTURE
(FROM NIST):
InChIKey:RDYMFSUJUZBWLH-AMHWMVONSA-N

Hcp d ln Hcp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.4 Shen and Wania 2005 L 143)
1.4 Shen and Wania 2005 L 144)
1.4 Muir et al. 2004 L 144)
1.4 Muir et al. 2004 L 143)
1.3 4200 Cetin et al. 2006 M
1.4 Altschuh et al. 1999 M
1.5×10−1 Rice et al. 1997b M 9)
1.5 Cotham and Bidleman 1989 V
3.4×10−1 Suntio et al. 1988 V 9)
1.3×10−1 2300 Rice et al. 1997a X 295)
9.2×10−1 Suntio et al. 1988 C
3200 Kühne et al. 2005 Q
2300 Kühne et al. 2005 ?

References

  • Altschuh, J., Brüggemann, R., Santl, H., Eichinger, G., and Piringer, O. G.: Henry's law constants for a diverse set of organic chemicals: Experimental determination and comparison of estimation methods, Chemosphere, 39, 1871-1887, doi:10.1016/S0045-6535(99)00082-X, 1999.
  • Cetin, B., Ozer, S., Sofuoglu, A., and Odabasi, M.: Determination of Henry's law constants of organochlorine pesticides in deionized and saline water as a function of temperature, Atmos. Environ., 40, 4538-4546, doi:10.1016/J.ATMOSENV.2006.04.009, 2006.
  • Cotham, W. E. and Bidleman, T. F.: Degradation of malathion, endosulfan, and fenvalerate in seawater and seawater/sediment microcosms, J. Agric. Food Chem., 37, 824-828, doi:10.1021/JF00087A055, 1989.
  • Kühne, R., Ebert, R.-U., and Schüürmann, G.: Prediction of the temperature dependency of Henry's law constant from chemical structure, Environ. Sci. Technol., 39, 6705-6711, doi:10.1021/ES050527H, 2005.
  • Muir, D. C. G., Teixeira, C., and Wania, F.: Empirical and modeling evidence of regional atmospheric transport of current-use pesticides, Environ. Toxicol. Chem., 23, 2421-2432, doi:10.1897/03-457, 2004.
  • Rice, C. P., Chernyak, S. M., Hapeman, C. J., and Biboulian, S.: Air-water distribution of the endosulfan isomers, J. Environ. Qual., 26, 1101-1106, doi:10.2134/jeq1997.00472425002600040022x, 1997a.
  • Rice, C. P., Chernyak, S. M., and McConnell, L. L.: Henry's law constants for pesticides measured as a function of temperature and salinity, J. Agric. Food Chem., 45, 2291-2298, doi:10.1021/JF960834U, 1997b.
  • Shen, L. and Wania, F.: Compilation, evaluation, and selection of physical-chemical property data for organochlorine pesticides, J. Chem. Eng. Data, 50, 742-768, doi:10.1021/JE049693F, 2005.
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., and Glotfelty, D.: Critical review of Henry's law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1-59, doi:10.1007/978-1-4612-3850-8_1, 1988.

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
143) Literature-derived value.
144) Final adjusted value.
295) Value given here as quoted by Staudinger and Roberts (2001).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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