The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

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1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Cross Sections

Quantum Yields


Contact, Impressum, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Br oxides / BrO / Wilmouth(1999)_228K_286-381nm(band peaks)

DATAFILE: BrO_Wilmouth(1999)_228K_286-381nm(band peaks).txt
NAME: bromine monoxide
AUTHOR(YEAR): Wilmouth(1999)
T: 228K
λ: 286-381nm(band peaks)
BIBLIOGRAPHY: D.M. Wilmouth, T.F. Hanisco, N.M. Donahue, and J.G. Anderson, "Fourier transform ultraviolet spectroscopy of the A 2Π 3/2 ← X 2Π 3/2 transition of BrO", J. Phys. Chem. A 103, 8935-8945 (1999); DOI: 10.1021/jp991651o
COMMENTS: Peak values for the (26,0)-(0,0) bands obtained by analysis of the own data and the data of

R.A. Cox, D.W. Sheppard, and M.P. Stevens, "Absorption coefficients and kinetics of the BrO radical using molecular modulation," J. Photochem. 19, 189-207 (1982); DOI: 10.1016/0047-2670(82)80022-1,

A. Wahner, A.R. Ravishankara, S. P. Sander, and R.R. Friedl, "Absorption cross section of BrO between 312 and 385 nm at 298 and 223 K," Chem. Phys. Lett. 152, 507-512 (1988); DOI: 10.1016/0009-2614(88)80450-0,

J.J. Orlando, J.B. Burkholder, A.M.R.P. Bopegedera, and C.J. Howard, "Infrared measurements of BrO (X 2Π3/2)," J. Mol. Spectrosc. 145, 278-289 (1991); DOI: 10.1016/0022-2852(91)90115-Q,

B. Laszlo, R.E. Huie, M.J. Kurylo, and A.W. Miziolek, "Kinetic study of the reactions of BrO and IO radicals," J. Geophys. Res. D 102, 1523-1532 (1997); DOI: 10.1029/96JD00458,

M.K. Gilles, J.B. Burkholder, A.R. Ravishankara, and S. Solomon, "Kinetics of the IO radical. 2. Reaction of IO with BrO," J. Phys. Chem. A 101, 5526-5534 (1997); DOI: 10.1021/jp9709159,

at a common resolution of 0.40 nm; uncertainties of the absorption cross sections (in %) are listed also

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